丁二硫醚

丁二硫醚或二丁基二硫是一种有机化合物，化学式为C₈H₁₈S₂。它可由正丁硫醇的氧化反应制得。^[4]它在二氯甲烷中可以被间氯过氧苯甲酸氧化，生成丁基硫代亚磺酸-S-丁酯。^[5]它和溴化苄、锌在三氯化铝催化下反应，可以得到苄基丁硫醚。^[6]

丁二硫醚
别名	二丁基二硫 二正丁基二硫 二正丁基二硫醚
识别
CAS号	629-45-8  Y
性质
化学式	C8H18S2
摩尔质量	178.36 g·mol⁻¹
密度	0.930 g·cm−3（20 °C）[1]
熔点	116—118 °C（389—391 K）[2]
沸点	228—230 °C（501—503 K）[3]
相关物质
相关化学品	丁硫醚（日语：ジブチルスルフィド）
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

参考文献

1. Gilman, Henry; Smith, Lloyd E.; Parker, Harold H. THE CONSTITUTION OF DISULFOXIDES. Journal of the American Chemical Society (American Chemical Society (ACS)). 1925, 47 (3): 851–860. ISSN 0002-7863. doi:10.1021/ja01680a037.
2. Habib Firouzabadi, Daryoush Mohajer, Mohsen Entezari-Moghadam. Barium Ferrate Monohydrate BaFeO 4 ·H 2 O, a Useful Oxidant for the Oxidation of Organic Compounds under Aprotic Conditions. Bulletin of the Chemical Society of Japan. 1988-06, 61 (6): 2185–2189 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.61.2185. （原始内容存档于2021-12-02） （英语）.
3. Hisashi Fujihara, Ryouichi Akaishi, Naomichi Furukawa. A Mild, High-Yield Conversion of Thiols into Disulfides Using Disulfide Dication Salt: A New Redox System. Bulletin of the Chemical Society of Japan. 1989-02, 62 (2): 616–617 [2021-12-10]. ISSN 0009-2673. doi:10.1246/bcsj.62.616. （原始内容存档于2021-12-02） （英语）.
4. Abhinandan D. Hudwekar, Praveen K. Verma, Jaspreet Kour, Shilpi Balgotra, Sanghapal D. Sawant. Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazoles, and Disulfides: Transition Metal-Free Oxidative Coupling of Primary Amines in Polyethylene Glycol at Room Temperature: Synthesis of Imines, Azobenzenes, Benzothiazole. European Journal of Organic Chemistry. 2019-02-14, 2019 (6): 1242–1250 [2021-12-10]. doi:10.1002/ejoc.201801610 （英语）.
5. Jinyue Su, Yatao Qiu, Kun Ma, Yiwu Yao, Zhen Wang, Xianling Li, Dayong Zhang, Zhengchao Tu, Sheng Jiang. Design, synthesis, and biological evaluation of largazole derivatives: alteration of the zinc-binding domain. Tetrahedron. 2014-10, 70 (42): 7763–7769 [2021-12-10]. doi:10.1016/j.tet.2014.05.078. （原始内容存档于2018-07-01） （英语）.
6. M. M. Lakouraj, B. Movassagh, Z. Fadaei. SYNTHESIS OF ORGANIC SULFIDES VIA Zn/AlCl 3 SYSTEM IN AQUEOUS MEDIA. Synthetic Communications. 2002-01, 32 (8): 1237–1242 [2021-12-10]. ISSN 0039-7911. doi:10.1081/SCC-120003615 （英语）.