正丁基鈉

正丁基鈉是一種有機鈉化合物，化學式為C₄H₉Na，它具有強鹼性，為聚合結構。它可由正丁基鋰和叔丁醇鈉反應製得。^[2]它和1-溴萘反應，可以得到1-溴丁烷和1-萘基鈉。^[3]

正丁基鈉
IUPAC名
別名	丁基鈉
識別
CAS號	3525-44-8  Y
PubChem	101040259
ChemSpider	11351318
SMILES	CCC[CH2].[Na]
InChI	1S/C4H9.Na/c1-3-4-2;/h1,3-4H2,2H3;
InChIKey	IRDQNLLVRXMERV-UHFFFAOYSA-N
性質
化學式	C4H9Na
摩爾質量	80.1 g·mol−1
外觀	白色固體[1]
危險性
GHS危險性符號
GHS提示詞	危險
若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

參考文獻

1. Martinez-Martinez, A. J.; Kennedy, A. R.; Mulvey, R. E.; O'Hara, C. T. Supplementary Material for Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation. Science. 13 November 2014, 346 (6211): 834–837. Bibcode:2014Sci...346..834M. PMID 25395533. S2CID 206561570. doi:10.1126/science.1259662.
2. Schade, Christian; Bauer, Walter; Von Ragué Schleyer, Paul (November 1985). "n-Butylsodium: The preparation, properties and NMR spectra of a hydrocarbon- and tetrahydrofuran-soluble reagent". Journal of Organometallic Chemistry. 295 (3): c25–c28. doi:10.1016/0022-328X(85)80326-0
3. Gilman, Henry; Moore, Fred W.; Baine, Ogden (September 1941). "Secondary and Tertiary Alkyllithium Compounds and Some Interconversion Reactions with Them". Journal of the American Chemical Society. 63 (9): 2479–2482. doi:10.1021/ja01854a046