Loading AI tools
Group of chemical elements From Wikipedia, the free encyclopedia
Group 9, by modern IUPAC numbering,[1] is a group (column) of chemical elements in the d-block of the periodic table. Members of Group 9 include cobalt (Co), rhodium (Rh), iridium (Ir) and meitnerium (Mt).[2][page needed] These elements are among the rarest of the transition metals.[3]
Group 9 in the periodic table | |||||||||
---|---|---|---|---|---|---|---|---|---|
| |||||||||
↓ Period | |||||||||
4 | Cobalt (Co) 27 Transition metal | ||||||||
5 | Rhodium (Rh) 45 Transition metal | ||||||||
6 | Iridium (Ir) 77 Transition metal | ||||||||
7 | Meitnerium (Mt) 109 unknown chemical properties | ||||||||
Legend
|
Like other groups, the members of this family show patterns in electron configuration, especially in the outermost shells, resulting in trends in chemical behavior; however, rhodium deviates from the pattern.
"Group 9" is the modern standard designation for this group, adopted by the IUPAC in 1990.[2] In the older group naming systems, this group was combined with group 8 (iron, ruthenium, osmium, and hassium) and group 10 (nickel, palladium, platinum, and darmstadtium) and called group "VIIIB" in the Chemical Abstracts Service (CAS) "U.S. system", or "VIII" in the old IUPAC (pre-1990) "European system" (and in Mendeleev's original table).
Cobalt compounds have been used for centuries to impart a rich blue color to glass, glazes, and ceramics. Cobalt has been detected in Egyptian sculpture, Persian jewelry from the third millennium BC, in the ruins of Pompeii, destroyed in 79 AD, and in China, dating from the Tang dynasty (618–907 AD) and the Ming dynasty (1368–1644 AD).[4]
Swedish chemist Georg Brandt (1694–1768) is credited with discovering cobalt c. 1735, showing it to be a previously unknown element, distinct from bismuth and other traditional metals. Brandt called it a new "semi-metal".[5][6] He showed that compounds of cobalt metal were the source of the blue color in glass, which previously had been attributed to the bismuth found with cobalt. Cobalt became the first metal to be discovered since the pre-historical period. All other known metals (iron, copper, silver, gold, zinc, mercury, tin, lead and bismuth) had no recorded discoverers.
Rhodium was discovered in 1803 by William Hyde Wollaston,[7] soon after he discovered palladium.[8][9][10] He used crude platinum ore presumably obtained from South America.[11] His procedure dissolved the ore in aqua regia and neutralized the acid with sodium hydroxide (NaOH). He then precipitated the platinum as ammonium chloroplatinate by adding ammonium chloride (NH
4Cl). Most other metals like copper, lead, palladium, and rhodium were precipitated with zinc. Diluted nitric acid dissolved all but palladium and rhodium. Of these, palladium dissolved in aqua regia but rhodium did not,[12] and the rhodium was precipitated by the addition of sodium chloride as Na
3[RhCl
6]·nH
2O. After being washed with ethanol, the rose-red precipitate was reacted with zinc, which displaced the rhodium in the ionic compound and thereby released the rhodium as free metal.[13]
Chemists who studied platinum dissolved it in aqua regia (a mixture of hydrochloric and nitric acids) to create soluble salts. They always observed a small amount of a dark, insoluble residue.[14] In 1803, British scientist Smithson Tennant (1761–1815) analyzed the insoluble residue and concluded that it must contain a new metal. Vauquelin treated the powder alternately with alkali and acids[15] and obtained a volatile new oxide, which he believed to be of this new metal—which he named ptene, from the Greek word πτηνός ptēnós, "winged".[16][13] Tennant, who had the advantage of a much greater amount of residue, continued his research and identified the two previously undiscovered elements in the black residue, iridium and osmium.[14][15] He obtained dark red crystals (probably of Na
2[IrCl
6]·nH
2O) by a sequence of reactions with sodium hydroxide and hydrochloric acid.[13] He named iridium after Iris (Ἶρις), the Greek winged goddess of the rainbow and the messenger of the Olympian gods, because many of the salts he obtained were strongly colored.[lower-alpha 1][17] Discovery of the new elements was documented in a letter to the Royal Society on June 21, 1804.[14][18]
Meitnerium was first synthesized on August 29, 1982, by a German research team led by Peter Armbruster and Gottfried Münzenberg at the Institute for Heavy Ion Research (Gesellschaft für Schwerionenforschung) in Darmstadt.[19] The team bombarded a target of bismuth-209 with accelerated nuclei of iron-58 and detected a single atom of the isotope meitnerium-266:[20]
This work was confirmed three years later at the Joint Institute for Nuclear Research at Dubna (then in the Soviet Union).[20]
Z | Element | No. of electrons per shell | M.P. | B.P. | Year of Discovery | Discoverer |
---|---|---|---|---|---|---|
27 | cobalt | 2, 8, 15, 2 | 1768 K 1495 °C | 3200 K 2927 °C | ~1735 | Georg Brandt |
45 | rhodium | 2, 8, 18, 16, 1 | 2237 K 1964 °C | 3968 K 3695 °C | 1803 | W. H. Wollaston |
77 | iridium | 2, 8, 18, 32, 15, 2 | 2719 K 2446 °C | 4403 K 4130 °C | 1803 | S. Tennant |
109 | meitnerium | 2, 8, 18, 32, 32, 15, 2[*] | — | — | 1982 | P. Armbruster and G. Münzenberg |
[*] Predicted.
The first three elements are hard silvery-white metals:
All known isotopes of meitnerium are radioactive with short half-lives. Only minute quantities have been synthesized in laboratories. It has not been isolated in pure form, and its physical and chemical properties have not been determined yet. [citation needed] Based on what is known, meitnerium is considered a homologue to iridium.
Of the group 9 elements, only cobalt has a biological role. It is a key constituent of cobalamin, also known as vitamin B12, the primary biological reservoir of cobalt as an ultratrace element.[21][22] Bacteria in the stomachs of ruminant animals convert cobalt salts into vitamin B12, a compound which can only be produced by bacteria or archaea. A minimal presence of cobalt in soils therefore markedly improves the health of grazing animals, and an uptake of 0.20 mg/kg a day is recommended, because they have no other source of vitamin B12.[23]
Proteins based on cobalamin use corrin to hold the cobalt. Coenzyme B12 features a reactive C-Co bond that participates in the reactions.[24] In humans, B12 has two types of alkyl ligand: methyl and adenosyl. MeB12 promotes methyl (−CH3) group transfers. The adenosyl version of B12 catalyzes rearrangements in which a hydrogen atom is directly transferred between two adjacent atoms with concomitant exchange of the second substituent, X, which may be a carbon atom with substituents, an oxygen atom of an alcohol, or an amine. Methylmalonyl coenzyme A mutase (MUT) converts MMl-CoA to Su-CoA, an important step in the extraction of energy from proteins and fats.[25]
Seamless Wikipedia browsing. On steroids.
Every time you click a link to Wikipedia, Wiktionary or Wikiquote in your browser's search results, it will show the modern Wikiwand interface.
Wikiwand extension is a five stars, simple, with minimum permission required to keep your browsing private, safe and transparent.