三氯化鎢是一種無機化合物,化學式為W6Cl18。它是一種八面體簇合物,為棕色固體,可由二氯化鎢的氯化反應得到。[2]這種簇合物有著12個雙氯橋配體,其結構和鈮或鉭的氯化物類似。相比之下,W6Cl12只有8個三氯橋。
六氯化鎢被鉍還原,可以得到混合價態W(III)-W(IV)的氯化物:[3]
- 9 WCl6 + 8 Bi → 3 W3Cl10 + 8 BiCl3
參考文獻
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