羊茅麦角碱

羊茅麦角碱（(8β,10β)-6,8-二甲基麦角灵）是一种有机化合物，化学式为C₁₆H₂₀N₂，它是一种麦角灵真菌分离物。^[2]它可以2-溴-3-硝基苄溴为原料经多步反应、柱分离制得。^[1]

羊茅麦角碱
IUPAC名 6,8β-Dimethylergoline
系统名 (6aR,9R,10aR)-7,9-Dimethyl-4,6,6a,7,8,9,10,10a-octahydroindolo[4,3-fg]quinoline
别名	狐茅麦角碱
识别
CAS号	569-26-6  Y
PubChem	332915
ChemSpider	294963
SMILES	C[C@@H]1C[C@@H]2c3cccc4c3c(c[nH]4)C[C@H]2N(C1)C
性质
化学式	C16H20N2
摩尔质量	240.34 g·mol−1
外观	白色固体[1]
熔点	236—240 °C（509—513 K）[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

参考文献

1. Liu, Haichao; Zhang, Xiwu; Shan, Dong; Pitchakuntla, Mallesham; Ma, Yongfan; Jia, Yanxing. Total Syntheses of Festuclavine, Pyroclavine, Costaclavine, epi-Costaclavine, Pibocin A, 9-Deacetoxyfumigaclavine C, Fumigaclavine G, and Dihydrosetoclavine. Organic Letters (American Chemical Society (ACS)). 2017-06-08, 19 (12): 3323–3326. ISSN 1523-7060. doi:10.1021/acs.orglett.7b01504.
2. Wallwey, C; Matuschek, M; Xie, XL; Li, SM. Ergot alkaloid biosynthesis in Aspergillus fumigatus: Conversion of chanoclavine-I aldehyde to festuclavine by the festuclavine synthase FgaFS in the presence of the old yellow enzyme FgaOx3. Organic & Biomolecular Chemistry. 2010, 8 (15): 3500–8. PMID 20526482. doi:10.1039/c003823g.