三硝酸氧钒

三硝酸氧钒
别名	硝酸钒酰; 硝酸氧钒(V)
识别
CAS号	16017-37-1
PubChem	135096579
ChemSpider	123483
SMILES	[V](O[N+]([O-])=O)(O[N+]([O-])=O)(O[N+]([O-])=O)=O;
InChI	1S/3NO3.O.V/c32-1(3)4;;/q3-1;;+3;
InChIKey	NRKQBMOGOKEWPX-UHFFFAOYSA-N
性质
化学式	VO(NO3)3
摩尔质量	252.953 g·mol⁻¹
外观	黄色液体
熔点	2 °C（275 K）
沸点	86—91 °C（359—364 K）（0.7 mmHg）
溶解性（水）	水
危险性
主要危害	氧化性
相关物质
相关化学品	niobium nitrate, vanadyl perchlorate
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

三硝酸氧钒（化学式：VO(NO₃)₃），是+5价钒的硝酸盐。它可由五氧化二氮和五氧化二钒反应得到。它是硝化试剂，可以和苯、苯酚、氯苯、苯甲醚、乙酰苯胺、苯甲酸、苯甲酸乙酯、甲苯等芳香烃发生硝化反应。^[2]

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VO(NO₃)₃可以将五氧化二钒浸入液态五氧化二氮，于室温反应两天得到。此法的产率约为85%：^[3]

V₂O₅ + 3N₂O₅ → 2VO(NO₃)₃.

通过真空蒸馏可以提纯产物。^[3]

VO(NO₃)₃也能由三氯氧钒VOCl₃和五氧化二氮反应得到。^[4]

参考文献

[1]
Dove, Michael F. A.; Berthold Manz; John Montgomery; Gerald Pattenden; Simon A. Wood. Vanadium(V) oxytrinitrate, VO(NO3)3. A powerful reagent for the nitration of aromatic compounds at room temperature under non-acidic conditions. Journal of the Chemical Society, Perkin Transactions 1. 1998, (10): 1589–1590. ISSN 0300-922X. doi:10.1039/A801771I.
[2]
Aitken, R. Alan; Alajarin, Mateo; Allen, D. W.; Mikael Begtrup; Daniel Bellus; J. Berna-Canovas; H. Boeckemeier; Stefan Bräse; I.R. Butler; Jose Chiara; Henri-J. Cristau; I. Gorrell; D. Keck; Terence Kee; Carmen Lopez-Leonardo; T. Muller; Patrick J. Murphy; Patrick O'Leary; Beate Priewisch; L.K. Rasmussen; Karola Rück-Braun; Bjoern Schlummer; Andreas Schmidt; Paul James Stevenson; J.C. Tebby; David Virieux. Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 31b: Arene-X (X=N, P). Georg Thieme Verlag. 2014-05-14: 1215 [29 September 2014]. ISBN 9783131720719. （原始内容存档于2017-04-10）.
[3]
Harris, Arlo D.; John C. Trebellas. AD296097 Experimental Studies of the Reactions of N2O5 with Metal Acid Anhydrides and BF3. Arlington Hall Station: Armed Services Technical Information Agency. 26 April 1962 [30 September 2014]. （原始内容存档于2016-03-03）.
[4]
Schmeisser, Martin. Die Chemie der anorganischen Acylnitrate (ein Problem des Nitrylchlorids) und Acylperchlorate (ein Problem des Dichlorhexoxyds). Angewandte Chemie. 1955, 67 (17–18): 493–501. ISSN 0044-8249. doi:10.1002/ange.19550671708 （德语）.

拓展阅读

Gmelin, Syst No 48, Teil A & Teil B (Lieferung 1 & 2) (1967); Teil A (Lieferung 1) & Teil A (Lieferung 2) (1968);& Erganzungwerk (Band2)(1971)
M. Schmeisser, "Chemical Abstracts", (1955), 49, 10873
L. Bretherick, Ed, "Hazards in the Chemical Laboratory", Royal Society of Chemistry, London, Engl (1979), pg. 1160

[Dove1998-1] [1]
Dove, Michael F. A.; Berthold Manz; John Montgomery; Gerald Pattenden; Simon A. Wood. Vanadium(V) oxytrinitrate, VO(NO3)3. A powerful reagent for the nitration of aromatic compounds at room temperature under non-acidic conditions. Journal of the Chemical Society, Perkin Transactions 1. 1998, (10): 1589–1590. ISSN 0300-922X. doi:10.1039/A801771I.

[AitkenAlajarin2014-2] [2]
Aitken, R. Alan; Alajarin, Mateo; Allen, D. W.; Mikael Begtrup; Daniel Bellus; J. Berna-Canovas; H. Boeckemeier; Stefan Bräse; I.R. Butler; Jose Chiara; Henri-J. Cristau; I. Gorrell; D. Keck; Terence Kee; Carmen Lopez-Leonardo; T. Muller; Patrick J. Murphy; Patrick O'Leary; Beate Priewisch; L.K. Rasmussen; Karola Rück-Braun; Bjoern Schlummer; Andreas Schmidt; Paul James Stevenson; J.C. Tebby; David Virieux. Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 31b: Arene-X (X=N, P). Georg Thieme Verlag. 2014-05-14: 1215 [29 September 2014]. ISBN 9783131720719. （原始内容存档于2017-04-10）.

[Harris62-3] [3]
Harris, Arlo D.; John C. Trebellas. AD296097 Experimental Studies of the Reactions of N2O5 with Metal Acid Anhydrides and BF3. Arlington Hall Station: Armed Services Technical Information Agency. 26 April 1962 [30 September 2014]. （原始内容存档于2016-03-03）.

[Schmeisser1955-4] [4]
Schmeisser, Martin. Die Chemie der anorganischen Acylnitrate (ein Problem des Nitrylchlorids) und Acylperchlorate (ein Problem des Dichlorhexoxyds). Angewandte Chemie. 1955, 67 (17–18): 493–501. ISSN 0044-8249. doi:10.1002/ange.19550671708 （德语）.

[2]

[1]

[3]

[4]