金屬唑

金屬唑（又稱金屬雜茂、金屬雜環戊二烯）是環戊二烯的衍生物，其中第5位置的碳原子——飽和碳——被雜原子替代。與其母體化合物不同，金屬唑從雜原子開始標數。有些化合物被描述為有機金屬化合物，但在下表中也出現幾個類金屬和非金屬以進行對比。^[1]許多金屬唑會發出熒光。吡咯和噻吩的高分子衍生物在分子電子學中成為研究對象。金屬唑可以視作吡咯的結構類似物，它們包括：

More information 名稱, M ...

一些C₄H₄MH金屬唑根據計算的幾何形狀和反轉障能E^[2]
名稱	M	d(M-C), Å	d(M-H), Å	α(C-M-C), °	E, kJ/mol
吡咯	N	1.37	1.01	110	0
磷唑	P	1.81	1.425	90.5	67
砷唑	As	1.94	1.53	86	125
銻唑	Sb	2.14	1.725	80.5	160
鉍唑	Bi	2.24	1.82	78	220

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砷唑，具有中度芳香性的砷類似物
鉍唑，鉍的類似物
硼唑，硼的類似物
呋喃（氧雜茂），氧的類似物
鎵唑，鎵的類似物
鍺唑，鍺的類似物
磷唑，磷的類似物
吡咯，氮的類似物
硒吩，硒的類似物
矽唑，矽的類似物
錫唑，錫的類似物
鐵唑（英語：Ferrole），鐵的類似物
銻唑，銻的類似物
碲吩，碲的類似物
鉛唑^[3]^[4]，鉛的類似物
噻吩，硫的類似物
鈦唑，鈦的類似物
鋯唑，鋯的類似物

參見

金屬環戊烷（英語：Metallacyclopentanes）

參考文獻

[1]
Tracy, Henry J.; Mullin, Jerome L.; Klooster, Wim T.; Martin, James A.; Haug, Judith; Wallace, Scott; Rudloe, Isaac; Watts, Kimberly. Enhanced Photoluminescence from Group 14 Metalloles in Aggregated and Solid Solutions. Inorganic Chemistry. 2005, 44 (6): 2003–2011. PMID 15762727. doi:10.1021/ic049034o.
[2]
Pelzer, Silke; Wichmann, Karin; Wesendrup, Ralf; Schwerdtfeger, Peter. Trends in Inversion Barriers IV. The Group 15 Analogous of Pyrrole. The Journal of Physical Chemistry A. 2002, 106 (26): 6387. Bibcode:2002JPCA..106.6387P. doi:10.1021/jp0203494.
[3]
Saito, Masaichi; Nakada, Marisa; Kuwabara, Takuya; Owada, Ryota; Furukawa, Shunsuke; Narayanan, Radhika; Abe, Minori; Hada, Masahiko; Tanaka, Ken; Yamamoto, Yoshihiko. Inverted Sandwich Rh Complex Bearing a Plumbole Ligand and Its Catalytic Activity. Organometallics. 2019-08-26, 38 (16): 3099–3103. ISSN 0276-7333. doi:10.1021/acs.organomet.9b00339.
[4]
Münzfeld, Luca; Sun, Xiaofei; Schlittenhardt, Sören; Schoo, Christoph; Hauser, Adrian; Gillhuber, Sebastian; Weigend, Florian; Ruben, Mario; Roesky, Peter W. Introduction of plumbole to f-element chemistry. Chemical Science. 2021-12-10 [2021-12-18]. ISSN 2041-6539. doi:10.1039/D1SC03805B. （原始內容存檔於2022-09-03）（英語）.
[5]
Dettlaf G, Weiss E. Crystal structure, proton NMR and mass spectrum of tricarbonylferracyclopentadienetricarbonyliron, C₄H₄Fe₂(CO)₆. J. Organomet. Chem. 1976, 108: 213–23. doi:10.1016/S0022-328X(00)82143-9.

[1] [1]
Tracy, Henry J.; Mullin, Jerome L.; Klooster, Wim T.; Martin, James A.; Haug, Judith; Wallace, Scott; Rudloe, Isaac; Watts, Kimberly. Enhanced Photoluminescence from Group 14 Metalloles in Aggregated and Solid Solutions. Inorganic Chemistry. 2005, 44 (6): 2003–2011. PMID 15762727. doi:10.1021/ic049034o.

[geo-2] [2]
Pelzer, Silke; Wichmann, Karin; Wesendrup, Ralf; Schwerdtfeger, Peter. Trends in Inversion Barriers IV. The Group 15 Analogous of Pyrrole. The Journal of Physical Chemistry A. 2002, 106 (26): 6387. Bibcode:2002JPCA..106.6387P. doi:10.1021/jp0203494.

[3] [3]
Saito, Masaichi; Nakada, Marisa; Kuwabara, Takuya; Owada, Ryota; Furukawa, Shunsuke; Narayanan, Radhika; Abe, Minori; Hada, Masahiko; Tanaka, Ken; Yamamoto, Yoshihiko. Inverted Sandwich Rh Complex Bearing a Plumbole Ligand and Its Catalytic Activity. Organometallics. 2019-08-26, 38 (16): 3099–3103. ISSN 0276-7333. doi:10.1021/acs.organomet.9b00339.

[4] [4]
Münzfeld, Luca; Sun, Xiaofei; Schlittenhardt, Sören; Schoo, Christoph; Hauser, Adrian; Gillhuber, Sebastian; Weigend, Florian; Ruben, Mario; Roesky, Peter W. Introduction of plumbole to f-element chemistry. Chemical Science. 2021-12-10 [2021-12-18]. ISSN 2041-6539. doi:10.1039/D1SC03805B. （原始內容存檔於2022-09-03）（英語）.

[5] [5]
Dettlaf G, Weiss E. Crystal structure, proton NMR and mass spectrum of tricarbonylferracyclopentadienetricarbonyliron, C₄H₄Fe₂(CO)₆. J. Organomet. Chem. 1976, 108: 213–23. doi:10.1016/S0022-328X(00)82143-9.

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