三氟乙酸亞鉈

三氟乙酸亞鉈是一種有機酸鹽，化學式為TlOCOCF₃。它可由碳酸亞鉈和三氟乙酸反應製得。^[2]

三氟乙酸亞鉈
識別
CAS號	2923-19-5  Y
性質
化學式	C2F3O2Tl
摩爾質量	317.4 g·mol−1
溶解性（水）	易溶[1]
若非註明，所有數據均出自標準狀態（25 ℃，100 kPa）下。

應用

它可用於製備三氟乙酸根的配合物，如它和[RhCl(C₂H₄)₂]₂在戊烷中反應，可以得到[Rh(OCOCF₃)(C₂H₄)₂]₂；^[3]它和[(C₃H₅)₃WCl]₂反應，可以得到(C₃H₅)₃WO₂CCF₃。^[4]

參考文獻

1. Swarts, F. Some trifluoroacetates. Bulletin des Societes Chimiques Belges (1939), 48, 176-191. ISSN 0037-9646
2. F. Albert Cotton, Naresh S. Dalal, Penglin Huang, Sergey A. Ibragimov, Carlos A. Murillo, Paula M. B. Piccoli, Chris M. Ramsey, Arthur J. Schultz, Xiaoping Wang, and Qinliang Zhao. Better Understanding of the Species with the Shortest Re₂⁶⁺ Bonds and Related Re₂⁷⁺ Species with Tetraguanidinate Paddlewheel Structures. Inorg. Chem. 2007, 46, 5, 1718–1726. doi:10.1021/ic062319b.
3. F. Bianchi; M.C. Gallazzi; L. Porri; P. Diversi (1980). Disproportionation of the cyclooctene ligand in the reaction of [IrCl(C8H14)2]2. With AgOCOCF3: formation of [Ir(OCOCF3)(C8H14)2]2 and [Ir(OCOCF3)(1,5-C8H12]2 and their conversion into cationic arene complexes. Journal of Organometallic Chemistry, 202(1), 99–105. doi:10.1016/s0022-328x(00)81387-x
4. F. Bianchi; M.C. Gallazzi; L. Porri; P. Diversi (1980). Disproportionation of the cyclooctene ligand in the reaction of [IrCl(C8H14)2]2. With AgOCOCF3: formation of [Ir(OCOCF3)(C8H14)2]2 and [Ir(OCOCF3)(1,5-C8H12]2 and their conversion into cationic arene complexes. Journal of Organometallic Chemistry, 202(1), 99–105. doi:10.1016/s0022-328x(00)81387-x