冈伯格二聚体

冈伯格二聚体
别名	1-二苯基亚甲基-4-三苯甲基-2,5-环己二烯; 3-三苯甲基-6-二苯亚甲基-1,4-环己二烯
识别
CAS号	18909-18-7
PubChem	140290
ChemSpider	123721
SMILES	C1=CC=C(C=C1)C(=C2C=CC(C=C2)C(C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5)C6=CC=CC=C6;
性质
化学式	C38H30
摩尔质量	486.64 g·mol−1
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

冈伯格二聚体是一种有机化合物，化学式为C₃₈H₃₀，其名称来自化学家摩西·冈伯格。它可以在三苯甲基自由基的聚合中产生：^[1]

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它也可由三苯基氯甲烷和锌反应得到。^[2]^[3]它和对苯醌在氘代二氯甲烷中反应，加入戊烷后可以沉淀出白色的1,4-二(三苯甲氧基)苯。^[4]

参见

六苯乙烷

参考文献

[1]
Pangia, Thomas M.; Davies, Casey G.; Prendergast, Joshua R.; Gordon, Jesse B.; Siegler, Maxime A.; Jameson, Guy N. L.; Goldberg, David P. Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex. Journal of the American Chemical Society. 28 March 2018, 140 (12): 4191–4194. PMC 6047074 . PMID 29537258. doi:10.1021/jacs.7b12707.
[2]
Abolghasem Bakhoda, Otome E. Okoromoba, Christine Greene, Mahdi Raghibi Boroujeni, Jeffery A. Bertke, Timothy H. Warren. Three-Coordinate Copper(II) Alkynyl Complex in C–C Bond Formation: The Sesquicentennial of the Glaser Coupling. Journal of the American Chemical Society. 2020-10-28, 142 (43): 18483–18490 [2021-01-09]. ISSN 0002-7863. doi:10.1021/jacs.0c07137. （原始内容存档于2020-10-31）（英语）.
[3]
Tobias Heurich, Vitaly Nesterov, Gregor Schnakenburg, Zheng-Wang Qu, Stefan Grimme, Khatera Hazin, Derek P. Gates, Marianne Engeser, Rainer Streubel. Strong Evidence of a Phosphanoxyl Complex: Formation, Bonding, and Reactivity of Ligated Phosphorus Analogues of Nitroxides. Angewandte Chemie International Edition. 2016-11-07, 55 (46): 14439–14443 [2021-01-09]. doi:10.1002/anie.201608169 （英语）.
[4]
Tao, Xin; Daniliuc, Constantin G.; Knitsch, Robert; Hansen, Michael Ryan; Eckert, Hellmut; Lübbesmeyer, Maximilian; Studer, Armido; Kehr, Gerald; Erker, Gerhard. The special role of B(C6F5)3 in the single electron reduction of quinones by radicals. Chemical Science. 2018, 9 (41): 8011–8018. ISSN 2041-6520. doi:10.1039/C8SC03005G.

[1] [1]
Pangia, Thomas M.; Davies, Casey G.; Prendergast, Joshua R.; Gordon, Jesse B.; Siegler, Maxime A.; Jameson, Guy N. L.; Goldberg, David P. Observation of Radical Rebound in a Mononuclear Nonheme Iron Model Complex. Journal of the American Chemical Society. 28 March 2018, 140 (12): 4191–4194. PMC 6047074 . PMID 29537258. doi:10.1021/jacs.7b12707.

[2] [2]
Abolghasem Bakhoda, Otome E. Okoromoba, Christine Greene, Mahdi Raghibi Boroujeni, Jeffery A. Bertke, Timothy H. Warren. Three-Coordinate Copper(II) Alkynyl Complex in C–C Bond Formation: The Sesquicentennial of the Glaser Coupling. Journal of the American Chemical Society. 2020-10-28, 142 (43): 18483–18490 [2021-01-09]. ISSN 0002-7863. doi:10.1021/jacs.0c07137. （原始内容存档于2020-10-31）（英语）.

[3] [3]
Tobias Heurich, Vitaly Nesterov, Gregor Schnakenburg, Zheng-Wang Qu, Stefan Grimme, Khatera Hazin, Derek P. Gates, Marianne Engeser, Rainer Streubel. Strong Evidence of a Phosphanoxyl Complex: Formation, Bonding, and Reactivity of Ligated Phosphorus Analogues of Nitroxides. Angewandte Chemie International Edition. 2016-11-07, 55 (46): 14439–14443 [2021-01-09]. doi:10.1002/anie.201608169 （英语）.

[4] [4]
Tao, Xin; Daniliuc, Constantin G.; Knitsch, Robert; Hansen, Michael Ryan; Eckert, Hellmut; Lübbesmeyer, Maximilian; Studer, Armido; Kehr, Gerald; Erker, Gerhard. The special role of B(C6F5)3 in the single electron reduction of quinones by radicals. Chemical Science. 2018, 9 (41): 8011–8018. ISSN 2041-6520. doi:10.1039/C8SC03005G.

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