Samarium(III) acetate

Samarium(III) acetate is an acetate salt of samarium, with the chemical formula of Sm(CH₃COO)₃. It exists in the hydrate and tetrahydrate form. Its tetrahydrate can be obtained by dissolving samarium(III) oxide in 50% acetic acid solution, crystallizing and vacuum drying.^{[1][unreliable source?]} The mixed anion acetate [Sm(CH₃COO)(H₂O)₆]Cl₂·H₂O and [Sm(CH₃COO)₂(H₂O)₃]Cl can be crystallized from SmCl₃·6H₂O and SmOCl in acetic acid solution respectively.^[2]

Samarium(III) acetate

Names
Other names Samarium ethanoate
Identifiers
CAS Number	10465-27-7 anhydrous Y hydrate: 100587-91-5 Y tetrahydrate: 15280-52-1 Y
3D model (JSmol)	Interactive image hydrate: Interactive image tetrahydrate: Interactive image
ChemSpider	23630 hydrate: 24590743
EC Number	233-950-1
PubChem CID	25297 hydrate: 71311371 tetrahydrate: 91886557
CompTox Dashboard (EPA)	DTXSID60890661
InChI InChI=1S/3C2H4O2.Sm/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3 Key: JPDBEEUPLFWHAJ-UHFFFAOYSA-K hydrate: InChI=1S/3C2H4O2.H2O.Sm/c3*1-2(3)4;;/h3*1H3,(H,3,4);1H2;/q;;;;+3/p-3 Key: LKSVMAKMHXTSQX-UHFFFAOYSA-K tetrahydrate: InChI=1S/3C2H4O2.4H2O.Sm/c3*1-2(3)4;;;;;/h3*1H3,(H,3,4);4*1H2; Key: NIVHQHOGEFRWEZ-UHFFFAOYSA-N
SMILES CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Sm+3] hydrate: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].O.[Sm+3] tetrahydrate: CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].O.O.O.O.[Sm+3]
Properties
Chemical formula	Sm(CH3COO)3
Molar mass	345.51[1]
Appearance	pale yellow powder
Density	1.94[1] g·cm−3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

References

1. "SAMARIUM ACETATE HYDRATE | 100587-91-5". ChemicalBook. Retrieved 2023-03-19.
2. Meyer G, Lossin A, Schleid T. Samarium (III) acetate-chloride hydrates: dimers and chains[J]. European Journal of Solid State and Inorganic Chemistry, 1991, 28(Suppl.): 529-534.