Rhenium tetraiodide

Chemical compound From Wikipedia, the free encyclopedia

Rhenium tetraiodide is a binary chemical compound of rhenium and iodide with the chemical formula ReI
4
.[1][2][3]

Quick Facts Names, Identifiers ...
Rhenium tetraiodide
Names
Other names
Rhenium(IV) iodide, tetraiodorhenium
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/4HI.Re/h4*1H;/q;;;;+4/p-4
    Key: KGKLLWHEYDUTBF-UHFFFAOYSA-J
  • I[Re](I)(I)I
Properties
I4Re
Molar mass 693.825 g·mol−1
Appearance black solid
Density g/cm3
reacts with water
Related compounds
Related compounds
Iridium tetraiodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Synthesis

Rhenium tetraiodide can be obtained via the reduction of perrhenic acid with hydrogen iodide:[4]

2HReO4 + 14HI4 → 2ReI4 + 3I2 + 8H2O

Physical properties

Rhenium tetraiodide forms black solid substance which is soluble in acetone and ether. Hydrolyzed by water, hygroscopic.[5]

Chemical properties

Rhenium tetraiodide is hydrolyzed by water:[5]

ReI4 + 2H2O → ReO2 + 4HI

Rhenium tetraiodide decomposes when heated:[5][6]

ReI4 → ReI3, ReI2, ReI, I2

References

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