Potassium carbonate

Potassium carbonate is the inorganic compound with the formula K₂CO₃. It is a white salt, which is soluble in water and forms a strongly alkaline solution. It is deliquescent, often appearing as a damp or wet solid. Potassium carbonate is mainly used in the production of soap and glass.^[3] Commonly, it can be found as the result of leakage of alkaline batteries.^[4]

Potassium carbonate

Names
IUPAC name Potassium carbonate
Other names Carbonate of potash, dipotassium carbonate, sub-carbonate of potash, pearl ash, potash, salt of tartar, salt of wormwood.
Identifiers
CAS Number	584-08-7 Y 6381-79-9 sesquihydrate Y
3D model (JSmol)	Interactive image
ChEBI	CHEBI:131526 N
ChemSpider	10949 Y
ECHA InfoCard	100.008.665
E number	E501(i) (acidity regulators, ...)
PubChem CID	11430
RTECS number	TS7750000
UNII	BQN1B9B9HA Y L9300DKS8U (sesquihydrate) Y
CompTox Dashboard (EPA)	DTXSID2036245
InChI InChI=1S/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 Y Key: BWHMMNNQKKPAPP-UHFFFAOYSA-L Y InChI=1/CH2O3.2K/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 Key: BWHMMNNQKKPAPP-NUQVWONBAS
SMILES C(=O)([O-])[O-].[K+].[K+]
Properties
Chemical formula	K 2CO 3
Molar mass	138.205 g/mol
Appearance	White, hygroscopic solid
Density	2.43 g/cm3
Melting point	891 °C (1,636 °F; 1,164 K)
Boiling point	Decomposes
Solubility in water	110.3 g/100 mL (20 °C) 149.2 g/100 mL (100 °C)
Solubility	3.11 g/100 mL (25 °C) methanol Insoluble in alcohol, acetone
Acidity (pKa)	10.25
Magnetic susceptibility (χ)	−59.0·10−6 cm3/mol
Thermochemistry[1]
Heat capacity (C)	114.4 J·mol−1·K−1
Std molar entropy (S⦵298)	155.5 J·mol−1·K−1
Std enthalpy of formation (ΔfH⦵298)	−1151.0 kJ·mol−1
Gibbs free energy (ΔfG⦵)	−1063.5 kJ·mol−1
Enthalpy of fusion (ΔfH⦵fus)	27.6 kJ·mol−1
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H302, H315, H319, H335
Precautionary statements	P261, P305+P351+P338
NFPA 704 (fire diamond)	2 0 0
Flash point	Non-flammable
Lethal dose or concentration (LD, LC):
LD50 (median dose)	1870 mg/kg (oral, rat)[2]
Safety data sheet (SDS)	ICSC 1588
Related compounds
Other anions	Potassium bicarbonate
Other cations	Lithium carbonate Sodium carbonate Rubidium carbonate Caesium carbonate
Related compounds	Ammonium carbonate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is YN ?) Infobox references

History

For a longer section on a related group of chemicals with much common history, see Potash § History.

Potassium carbonate is the primary component of potash and the more refined pearl ash or salts of tartar. Historically, pearl ash was created by baking potash in a kiln to remove impurities. The fine, white powder remaining was the pearl ash. The first patent issued by the US Patent Office was awarded to Samuel Hopkins in 1790 for an improved method of making potash and pearl ash.^[5]

In late 18th-century North America, before the development of baking powder, pearl ash was used as a leavening agent for quick breads.^[6][7]

Production

The modern commercial production of potassium carbonate is by reaction of potassium hydroxide with carbon dioxide:^[3]

2 KOH + CO₂ → K₂CO₃ + H₂O

From the solution crystallizes the sesquihydrate K₂CO₃·3⁄2H₂O ("potash hydrate"). Heating this solid above 200 °C (392 °F) gives the anhydrous salt. In an alternative method, potassium chloride is treated with carbon dioxide in the presence of an organic amine to give potassium bicarbonate, which is then calcined:

2 KHCO₃ → K₂CO₃ + H₂O + CO₂

Applications

• (historically) for soap, glass, and dishware production
• as a mild drying agent where other drying agents, such as calcium chloride and magnesium sulfate, may be incompatible. It is not suitable for acidic compounds, but can be useful for drying an organic phase if one has a small amount of acidic impurity. It may also be used to dry some ketones, alcohols, and amines prior to distillation.^[8]
• in cuisine, where it has many traditional uses. It is used in some types of Chinese noodles and mooncakes, as well as Asian grass jelly and Japanese ramen. German gingerbread recipes often use potassium carbonate as a baking agent, although in combination with hartshorn.
• in the alkalization of cocoa powder to produce Dutch process chocolate by balancing the pH (i.e., reduce the acidity) of natural cocoa beans; it also enhances aroma. The process of adding potassium carbonate to cocoa powder is usually called "Dutching" (and the products referred to as Dutch-processed cocoa powder), as the process was first developed in 1828 by Dutchman Coenraad Johannes van Houten.
• as a buffering agent in the production of mead or wine.
• in antique documents, it is reported to have been used to soften hard water.^[9]
• as a fire suppressant in extinguishing deep-fat fryers and various other B class-related fires.
• in condensed aerosol fire suppression, although as the byproduct of potassium nitrate.
• as an ingredient in welding fluxes, and in the flux coating on arc-welding rods.
• as an animal feed ingredient to satisfy the potassium requirements of farmed animals such as broiler breeder chickens.
• as an acidity regulator in Swedish snus snuff tobacco

References

1. CRC handbook of chemistry and physics: a ready-reference book of chemical and physical data. William M. Haynes, David R. Lide, Thomas J. Bruno (2016-2017, 97th ed.). Boca Raton, Florida. 2016. ISBN 978-1-4987-5428-6. OCLC 930681942.{{cite book}}: CS1 maint: location missing publisher (link) CS1 maint: others (link)
2. Chambers, Michael. "ChemIDplus - 584-08-7 - BWHMMNNQKKPAPP-UHFFFAOYSA-L - Potassium carbonate [USP] - Similar structures search, synonyms, formulas, resource links, and other chemical information". chem.sis.nlm.nih.gov. Archived from the original on 2014-08-12.
3. H. Schultz; G. Bauer; E. Schachl; F. Hagedorn; P. Schmittinger (2005). "Potassium Compounds". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a22_039. ISBN 3-527-30673-0.
4. List, Jenny (October 19, 2022). "Crusty Leaking Cells Kill Your Tech. Just What's Going On?". Hackaday. Archived from the original on May 30, 2023.
5. "Milestones in U.S. patenting". www.uspto.gov. Retrieved 2023-08-04.
6. See references to "pearl ash" in "American Cookery" by Amelia Simmons, printed by Hudson & Goodwin, Hartford, 1796.
7. Civitello, Linda (2017). Baking powder wars: the cutthroat food fight that revolutionized cooking. Urbana, Illinois: University of Illinois Press. pp. 18–22. ISBN 978-0-252-04108-2.
8. Leonard, J.; Lygo, B.; Procter, G. "Advanced Practical Organic Chemistry" 1998, Stanley Thomas Publishers Ltd
9. Child, Lydia M. "The American Frugal Housewife" 1832

Bibliography

• A Dictionary of Science, Oxford University Press, New York, 2004
• Yu. Platonov, Andrew; Evdokimov, Andrey; Kurzin, Alexander; D. Maiyorova, Helen (29 June 2002). "Solubility of Potassium Carbonate and Potassium Hydrocarbonate in Methanol". Journal of Chemical & Engineering Data. 47 (5): 1175–1176. doi:10.1021/je020012v.

External links

• International Chemical Safety Card 1588