Epoxy value

Epoxy value derives from the Epoxy equivalent weight (EEW) or Weight Per Epoxide (WPE) and is a measure of the epoxy content of an epoxy resin or epoxy reactive diluent, or glycidyl ether.^[1] This is an important parameter as it allows determination of the correct mix ratio of an epoxy system with a curing agent.^[2] The epoxide equivalent weight is usually measured first and done by titration. The standard test method is ASTM D1652 though this has been modified by certain states of the USA.^[3] The epoxy equivalent weight (EEW) maybe defined as: the number of grams of epoxy resin required to give 1 mole of epoxy groups.^[4] The epoxy value is defined as the number of moles of epoxy group per 100g resin.^[5]

Example calculations

Polyoxypropylene diglycidyl ether, a reactive diluent with the trade name of Diluent F, has an average molecular weight of 1000 and a functionality of 2 so the EEW is 1000/2 = 500. The epoxy value is defined as the number of moles of epoxy group per 100g resin. So as an example using an epoxy resin with molar mass of 382 and that has 2 moles of epoxy groups per mole of resin, the EEW = 382/2 = 191, and the epoxy value is calculated as follows: 100/191 = 0.53 (i.e. the epoxy value of the resin is 0.53).^[6]

Alternative techniques

There are methods using instruments that do not use traditional titration techniques to determine epoxide equivalent weights.^[7]

Structure of bisphenol-A diglycidyl ether epoxy resin: n denotes the number of polymerized subunits and is typically in the range from 0 to 25

See also-related test methods

• Acid value
• Amine value
• Hydroxyl value
• Iodine value
• Peroxide value
• Saponification value

References

1. Howarth, G.A (1995). "5". In Karsa, D.R; Davies, W.D (eds.). Waterborne Maintenance Systems for Concrete and Metal Structures. Vol. 165. Cambridge, U.K: The Royal Society of Chemistry. ISBN 0-85404-740-9.
2. "How do you know how much hardener to mix with how much resin?:Ask the Doctor". www.mereco.com. Archived from the original on 2022-09-13. Retrieved 2021-08-01.
3. "Determining Epoxide Equivalent and Amine Value of Resins" (PDF). Texas.gov.
4. Spyrou, Emmanouil (2012). Powder coatings chemistry and technology. Hanover. p. 129. ISBN 978-3-86630-884-8. OCLC 828194496.{{cite book}}: CS1 maint: location missing publisher (link)
5. Howarth, GA. Master of Science thesis "The synthesis of a legislation compliant corrosion protection paint system, based on waterborne epoxy, urethane and oxazolidine technology". April 1997 Imperial College London Chapter 2.1.1 page 32
6. Müller, Bodo (2006). Coatings formulation : an international textbook. Urlich Poth. Hannover: Vincentz. p. 111. ISBN 3-87870-177-2. OCLC 76886114.
7. MONIZ, W. B.; PORANSKI, C. F. (1979-12-03), "Epoxide Equivalent Weight Determination by Carbon-13 Nuclear Magnetic Resonance", Epoxy Resin Chemistry, ACS Symposium Series, vol. 114, AMERICAN CHEMICAL SOCIETY, pp. 83–90, doi:10.1021/bk-1979-0114.ch007, ISBN 978-0-8412-0525-3, retrieved 2022-03-23

Further reading

• "Amines | Introduction to Chemistry". courses.lumenlearning.com. Retrieved 2021-07-22.
• Epoxy resin technology. Paul F. Bruins, Polytechnic Institute of Brooklyn. New York: Interscience Publishers. 1968. ISBN 0-470-11390-1. OCLC 182890.{{cite book}}: CS1 maint: others (link)
• Flick, Ernest W. (1993). Epoxy resins, curing agents, compounds, and modifiers : an industrial guide. Park Ridge, NJ. ISBN 978-0-8155-1708-5. OCLC 915134542.{{cite book}}: CS1 maint: location missing publisher (link)
• Lee, Henry (1967). Handbook of epoxy resins. Kris Neville ([2nd, expanded work] ed.). New York: McGraw-Hill. ISBN 0-07-036997-6. OCLC 311631322.