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Chemical compound From Wikipedia, the free encyclopedia
Diethylhydroxylamine (DEHA) is an organic compound with the formula (C2H5)2NOH. Strictly, this is N,N-diethylhydroxylamine. It has an isomer, N,O-diethylhydroxylamine with the formula EtNHOEt. Pure N,N-diethylhydroxylamine is a colorless liquid, although it is usually encountered as a colourless-to-yellow solution in water with an amine-like odor.
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| Names | |||
|---|---|---|---|
| Preferred IUPAC name
N-Ethyl-N-hydroxyethanamine | |||
| Identifiers | |||
3D model (JSmol) |
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| 1731349 | |||
| ChemSpider | |||
| ECHA InfoCard | 100.020.960 | ||
| EC Number |
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| MeSH | N,N-diethylhydroxylamine | ||
PubChem CID |
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| RTECS number |
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| UNII | |||
| UN number | 1993 | ||
CompTox Dashboard (EPA) |
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| Properties | |||
| C4H11NO | |||
| Molar mass | 89.138 g·mol−1 | ||
| Appearance | Colorless liquid | ||
| Odor | Ammoniacal | ||
| Density | 867 mg mL−1 | ||
| Melting point | −26 to −25 °C (−15 to −13 °F; 247 to 248 K) | ||
| Boiling point | 127.6 °C; 261.6 °F; 400.7 K | ||
| Miscible | |||
| Vapor pressure | 500 Pa (at 0 °C) | ||
| Acidity (pKa) | 5.67 (est) [1] | ||
| Thermochemistry | |||
Heat capacity (C) |
370.8 J K−1 mol−1 | ||
Std enthalpy of formation (ΔfH⦵298) |
−175.47–−174.03 kJ mol−1 | ||
Std enthalpy of combustion (ΔcH⦵298) |
−2.97201–−2.97069 MJ mol−1 | ||
| Hazards | |||
| GHS labelling: | |||
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| Warning | |||
| H226, H312, H315, H319, H332 | |||
| P280, P305+P351+P338 | |||
| Explosive limits | 1.9–10% | ||
| Lethal dose or concentration (LD, LC): | |||
LD50 (median dose) |
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| Related compounds | |||
Related alkanols |
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Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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DEHA can be synthesised from a reaction between triethylamine and a peroxide.
DEHA is largely used as an oxygen scavenger in water treatment.
It is a volatile oxygen scavenger[2][3] and reacts in a ratio of 2.8/1 DEHA/O2. It is employed in high pressure (>70 bar) boiler systems due to a very low rate of reaction at low temperatures and pressures. Due to its volatility, it acts as an oxygen scavenger throughout the entire boiler system due to steam carryover.
DEHA also reacts with ferrous metals to form a passivized film of magnetite throughout the boiler system. The reduction of toxic heavy metals, such as hexavalent chromium to their more environmentally-friendly counterparts like trivalent chromium, is also performed using aqueous solutions containing DEHA.
Several other applications include its use as:
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