Borate nitrate

Borate nitrates are mixed anion compounds containing separate borate and nitrate anions.

List

	chem	mw	crystal system	space group	unit cell Å	volume	density	comment	references
	Na3(NO3)[B6O10]								[1]
	K3B6O10NO3								[2]
	K3Na[B6O9(OH)3]NO3			Pnnm	a=13.208, b=9.107, c=12.325 Z=4				[3]
	Co3B7O13NO3								[4]
	[Co(H2O)6](NO3)2·[Co{B3O3(OH)4}2(H2O)4]·2H2O								[5]
	[Ni(H2O)6](NO3)2·[Ni{B3O3(OH)4}2(H2O)4]·2H2O								[5]
	Ni3B7O13NO3								[4]
	K7Ni[B18O24(OH)9](NO3)6· (H3BO3)	1497.96	trigonal	R3	a=12.2229 c=54.784 Z=6	7088	2.11	green	[6]
	Cu3B7O13NO3								[4]
	Zn3B7O13NO3								[4]
	[Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O		monoclinic	P21/c	a = 11.282, b = 6.5374, c = 17.668, β = 100.981°				[5]
	Rb3(NO3)[B6O10]								[2]
	Ag12(B9O18)(NO3)3		hexagonal	P63/m	a = 11.2896 c = 11.6693				[7]
	Cd3B7O13NO3								[4]
	La[B5O8(OH)]NO3
	La[B5O8(OH)]NO3·2H2O		monoclinic	P21/n	a=6.540, b=15.550, c=10.672, β=90.44° and Z=4				[8]
cerium(III) aquahydroxidooctaoxidopentaborate nitrate dihydrate	Ce[B5O8(OH)(H2O)]NO3·2H2O	455.24	monoclinic	P21/n	a=6.444 b=15.572 c=10.745 β=90.395 Z=4	1078.2	2.904	colourless	[9]
	Pr[B5O8(OH)(H2O)x]NO3·2H2O		monoclinic	P21/n	a=6.419, b=15.518, c=10.684, with β=90.54° Z=4	1064.3			[10]
	Pr7(BO3)3(NO3)N3O		hexagonal	P63	a=10.6834 c=6.6752 Z=2		6.457	green; contains N(OBO3)3 clusters, oxide and nitride	[11]
	Nd7(BO3)3(NO3)N3O		hexagonal	P63	a=10.6446 c=6.6339 Z=2		6.664	purplish-blue;contains N(OBO3)3 clusters oxide, and nitride;SHG	[11]
	Nd[B5O8(OH)(H2O)x]NO3·2H2O			P21/n	a = 6.4285, b = 15.5258, c = 10.7052, β = 90.39°	1068.44			[12]
	Sm[B5O8(OH)(H2O)x]NO3·2H2O			P21/n	a = 6.4409, b = 15.4199, c = 10.5097, β = 90.33°	1043.79			[12]
	Lu2B2O5(NO3)2·2H2O		triclinic	P1	a=7.8952, b=9.8862, c=14.6033, α=90.83, β=101.75, γ=110.02° Z=4				[6][13]
	Pb2(BO3)(NO3)	535.20	hexagonal	P63mc	a=5.0731 c=13.040 Z=2	290.64	6.116	colourless SHG 9×KDP	[14]
	[Pb3(B3O7)](NO3)	828.01		Pnma	a=10.3481 b=7.8908 c=11.2123 Z=4	914.54	6.007	colourless	[15]

References

1. Ortner, Teresa S.; Schildhammer, Daniel; Tribus, Martina; Joachim, Bastian; Huppertz, Hubert (2017-03-01). "Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10]NO3 (x=0.5, 0.6, 0.7)". Zeitschrift für Naturforschung B. 72 (3): 215–223. doi:10.1515/znb-2016-0242. ISSN 1865-7117. S2CID 99165997.
2. Zhang, Qiqi; Zhang, Fangfang; Li, Fuming; Han, Shujuan; Yang, Zhihua; Pan, Shilie (2021-02-13). "M3B6O10NO3 (M = K, Rb): Two new alkali metal borate-nitrates with noncentrosymmetric structures". European Journal of Inorganic Chemistry. 2021 (13): 1297–1304. doi:10.1002/ejic.202001167. ISSN 1434-1948. S2CID 233784768.
3. Ortner, Teresa S.; Wurst, Klaus; Perfler, Lukas; Tribus, Martina; Huppertz, Hubert (January 2015). "Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3". Journal of Solid State Chemistry. 221: 66–72. Bibcode:2015JSSCh.221...66O. doi:10.1016/j.jssc.2014.09.016.
4. Bither, Tom A.; Young, Howard S. (1974-08-01). "Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F". Journal of Solid State Chemistry. 10 (4): 302–311. Bibcode:1974JSSCh..10..302B. doi:10.1016/0022-4596(74)90039-5. ISSN 0022-4596.
5. Liu, Ying; Deng, Jun-Xia; Pan, Chun-Yang (2020-05-04). "Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant". Journal of Cluster Science. 32 (2): 469–477. doi:10.1007/s10876-020-01806-7. ISSN 1040-7278. S2CID 218495402.
6. Zoller, Michael; Wurst, Klaus; Huppertz, Hubert (2019-10-25). "Synthesis of the first nickel borate nitrate K7Ni[B18O24(OH)9](NO3)6· (H3BO3)". Zeitschrift für Naturforschung B. 74 (10): 757–764. doi:10.1515/znb-2019-0126. ISSN 1865-7117. S2CID 202872565. CC-BY can use images
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8. Zhao, Biao-Chun; Sun, Wei; Ren, Wei-Jian; Huang, Ya-Xi; Li, Zucheng; Pan, Yuanming; Mi, Jin-Xiao (October 2013). "Hygroscopic La[B5O8(OH)]NO3·2H2O: Insight into the evolution of borate fundamental building blocks". Journal of Solid State Chemistry. 206: 91–98. Bibcode:2013JSSCh.206...91Z. doi:10.1016/j.jssc.2013.07.032.
9. Sun, Wei; Zhu, Teng-Teng; Zhao, Biao-Chun; Huang, Ya-Xi; Mi, Jin-Xiao (2012-05-15). "Redetermination of Ce[B 5 O 8 (OH)(H 2 O)]NO 3 ·2H 2 O". Acta Crystallographica Section E. 68 (5): i33–i34. doi:10.1107/S1600536812016169. ISSN 1600-5368. PMC 3344287. PMID 22590053.
10. Ortner, Teresa S.; Huppertz, Hubert (2017-09-26). "Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87]NO3·2H2O". Zeitschrift für Naturforschung B. 72 (9): 677–685. doi:10.1515/znb-2017-0121. ISSN 1865-7117. S2CID 103777780.
11. Katrych, Sergiy; Arakcheeva, Alla; Sienkiewicz, Andrzej; Forró, László; Ivšić, Trpimir (2020-12-15). "High-Pressure Synthesis of Rare-Earth Borate-Nitrate Crystals for Second Harmonic Generation". Inorganic Chemistry. 60 (1): 286–291. doi:10.1021/acs.inorgchem.0c02909. ISSN 0020-1669. PMID 33320648. S2CID 229283287.
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14. Song, Jun-Ling; Hu, Chun-Li; Xu, Xiang; Kong, Fang; Mao, Jiang-Gao (2015-03-16). "A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units". Angewandte Chemie. 127 (12): 3750–3753. Bibcode:2015AngCh.127.3750S. doi:10.1002/ange.201412344.
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