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Enzo Artoni and Ignacio González King were the defending champions, but did not compete this year.
| Doubles | |
|---|---|
| 2005 Copa Petrobras Santiago | |
| Champions |  Daniel Köllerer Oliver Marach |
| Runners-up |  Lucas Arnold Ker Giovanni Lapentti |
| Score | 6–4, 6–3 |
Daniel Köllerer and Oliver Marach defeated Lucas Arnold Ker and Giovanni Lapentti 6–4, 6–3 in the final.
- 1.
Lucas Arnold Ker / 
Giovanni Lapentti (final) - 2.
Rubén Ramírez Hidalgo / Santiago Ventura (first round) - 3.
Marcelo Melo / Sergio Roitman (quarterfinals) - 4.
Marcos Daniel/ Fernando Vicente(withdrew due to a back injury for Daniel)
Key
- Q = Qualifier
- WC = Wild card
- LL = Lucky loser
- Alt = Alternate
- SE = Special exempt
- PR = Protected ranking
- ITF = ITF entry
- JE = Junior exempt
- w/o = Walkover
- r = Retired
- d = Defaulted
- SR = Special ranking
Draw
| First round | Quarterfinals | Semifinals | Final | ||||||||||||||||||||||||
| 1 | L Arnold Ker G Lapentti
| 77 | 710 | ||||||||||||||||||||||||
| WC |  T Bellucci A Ghem
| 62 | 68 | 1 | L Arnold Ker G Lapentti
| 79 | 61 | 6 | |||||||||||||||||||
 P Capdeville A García
| 711 | 3 | 1r | WC | J Aguilar F Parada
| 67 | 77 | 4 | |||||||||||||||||||
| WC | J Aguilar F Parada
| 69 | 6 | 2 | 1 | L Arnold Ker G Lapentti
| 6 | 7 | |||||||||||||||||||
| 3 | M Melo S Roitman
| 6 | 6 | WC | H Gamonal D Vemić
| 2 | 5 | ||||||||||||||||||||
 G Moraru A Ungur
| 0 | 3 | 3 | M Melo S Roitman
| 3 | 6 | 64 | ||||||||||||||||||||
| WC | H Gamonal D Vemić
| 6 | 6 | WC | H Gamonal D Vemić
| 6 | 4 | 77 | |||||||||||||||||||
 H Armando C Villagrán
| 3 | 1 | 1 | L Arnold Ker G Lapentti
| 4 | 3 | |||||||||||||||||||||
 Ó Hernández F Luzzi
| 3 | 6 | 6 | D Köllerer O Marach
| 6 | 6 | |||||||||||||||||||||
D Gimeno-Traver JA Marín
| 6 | 4 | 3 | Ó Hernández F Luzzi
| 6 | 6 | |||||||||||||||||||||
| D Hartfield J Silva
| 6 | 6 | D Hartfield J Silva
| 3 | 3 | ||||||||||||||||||||||
| Alt |  F Urban S Vagnozzi
| 2 | 1 | Ó Hernández F Luzzi
| 1 | 3 | |||||||||||||||||||||
JM del Potro S González
| 6 | 63 | 7 | D Köllerer O Marach
| 6 | 6 | |||||||||||||||||||||
| A Cruciat B Pašanski
| 2 | 77 | 5 | JM del Potro S González
| 6 | 5 | 65 | ||||||||||||||||||||
| D Köllerer O Marach
| 6 | 6 | D Köllerer O Marach
| 1 | 7 | 77 | |||||||||||||||||||||
| 2 | R Ramírez Hidalgo S Ventura
| 1 | 4 | ||||||||||||||||||||||||
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