1-Butyl-3-methylimidazolium tetrachloroferrate

Magnetic liquid From Wikipedia, the free encyclopedia

1-Butyl-3-methylimidazolium tetrachloroferrate is a magnetic ionic liquid. It can be obtained from 1-butyl-3-methylimidazolium chloride and ferric chloride. It has quite low water solubility.[1][2]

Quick Facts Identifiers, Properties ...
1-Butyl-3-methylimidazolium tetrachloroferrate
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Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.203.250
EC Number
  • 678-175-3
  • InChI=1S/C8H15N2.4ClH.Fe/c1-3-4-5-10-7-6-9(2)8-10;;;;;/h6-8H,3-5H2,1-2H3;4*1H;/q+1;;;;;+3/p-4
    Key: FYHLFBVHUIJIII-UHFFFAOYSA-J
  • CCCCN1C=C[N+](=C1)C.Cl[Fe-](Cl)(Cl)Cl
Properties
C8H15Cl4FeN2
Molar mass 336.87 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Due to the presence of the high spin FeCl4 anion, the liquid is paramagnetic and a magnetic susceptibility of 40.6 × 10−6 emu g−1 is reported. A simple small neodymium magnet suffices to attract the liquid in a test tube.

References

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