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Sulfenyl chloride
Chemical group (R–S–Cl) / From Wikipedia, the free encyclopedia
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In organosulfur chemistry, a sulfenyl chloride is a functional group with the connectivity R−S−Cl, where R is alkyl[1] or aryl. Sulfenyl chlorides are reactive compounds that behave as sources of RS+. They are used in the formation of RS−N and RS−O bonds. According to IUPAC nomenclature they are named as alkyl thiohypochlorites, i.e. esters of thiohypochlorous acid.
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Typically, sulfenyl halides are stabilized by electronegative substituents. This trend is illustrated by the stability of CCl3SCl obtained by chlorination of carbon disulfide.