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Compound with phosphate and sulfate ions From Wikipedia, the free encyclopedia
The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.
Some hydrogen phosphate sulfates are superprotonic conductors.
chem | mw | crystal system | space group | unit cell | volume | density | comment | references | |
---|---|---|---|---|---|---|---|---|---|
Sanjuanite | Al2(PO4)(SO4)(OH)·9H2O | [1] | |||||||
Hotsonite | Al11(SO4)3(PO4)2(OH)21 · 16H2O | triclinic | a=11.23, b=11.66 c=10.55 α=112° 32′, β=107° 32′ γ=64° 27′ | refract: α = 1.519 γ = 1.521 | [2] | ||||
Arangasite | Al2F(PO4)(SO4)·9H2O | monoclinic | P2/a | a = 7.073, b = 9.634, c = 10.827, β = 100.40°, Z = 2 | 725.7 | [3] | |||
peisleyite | Na3Al16(SO4)2(PO4)10(OH)17 · 20H2O | monoclinic | a 13.31, b 12.62, c 23.15, β 110.0°, Z = 2 | discredited | [4] | ||||
peisleyite | Na2Al9[(P,S)O4]8(OH)6·28H2O | triclinic | P1 | a = 9.28, b = 11.98, c = 13.25, α = 91.3, β = 75.6, γ = 67.67°, Z = 4 | 1308 | [5] | |||
Woodhouseite | CaAl3(PO4)(SO4)(OH)6 | trigonal | R3m | a = 6.993, c = 16.386 | 693.95 | 3.0 | Uniaxial (+) nω = 1.636 nε = 1.647 Birefringence: δ = 0.011 | [6] | |
Ardéalite | Ca2H(PO4)(SO4)•4H2O | monoclinic | a = 5.721, b = 30.95, c = 6.265, β= 117.26° Z = 4 | 986.11 | 2.32 | [7] | |||
Destinezite Diadochite | Fe2(PO4)(SO4)(OH)•6H2O | triclinic | P1 | a = 9.570, b = 9.716, c = 7.313, α = 98.74°, β = 107.90°, γ = 63.86° Z = 2 | [8] | ||||
bohuslavite | FeIII4(PO4)3(SO4)(OH)(H2O)10·nH2O (5 ≤ n ≤ 14) | triclinic | P1 | a = 13.376 b = 13.338 c = 10.863 α = 92.80, β = 91.03, γ = 119.92°, Z = 2 | 1675.7 | pink | [9] | ||
Borickyite | (Ca,Mg)(Fe3+,Al)4(PO4,SO4,CO3)(OH)8·3–7.5H2O | [10] | |||||||
Camaronesite | [Fe3+(H2O)2(PO3OH)]2(SO4)·1–2H2O | trigonal | R32 | a = 9.0833, c = 42.944, Z = 9 | 3068.5 | [11] | |||
Fe3+4(PO4)3(SO4)(OH)·18H2O | triclinic | P1 | a=13.376, b 13.338, c 10.863, α 92.80, β 91.03, γ 119.92° | 1675.7 | [12] | ||||
vanderheydenite | Zn6(PO4)2(SO4)(OH)4·7H2O | monoclinic | P21/n | a = 6.204 b = 19.619, c = 7.782, β = 90.67° | 947.1 | biaxial (–) α = 1.565, β = 1.580 γ = 1.582. 2V = 39.8° | [13] | ||
Svanbergite | SrAl3(PO4)(SO4)(OH)6 | trigonal | R3m | a = 6.97, c = 16.59 Z=3 | 697.98 | 3.2 | Uniaxial (+) nω = 1.631 - 1.635 nε = 1.646 - 1.649 Birefringence: δ = 0.015 | [14] | |
Birchite | Cd2Cu2(PO4)2(SO4) ·5H2O | a = 10.489 b = 20.901 c = 6.155 Z=4 | 1349.6 | 3.647 | biaxial positive,
nα = 1.624, nβ = 1.636, nγ = 1.669, 2Vcalc = +63°. |
[15] | |||
Corkite | PbFe3(OH)6SO4PO4 | trigonal | R3m | a = 7.32, c = 17.02 Z=3 | 781.2 | 4.295 | Uniaxial (-) nω = 1.930 nε = 1.930 n = 1.93 - 1.96 Birefringence 0.03 | [16] | |
BaAl3(PO4)(SO4)(OH)6 | trigonal | R3m | a = , c = Z=3 | [17] | |||||
hinsdalite | (Pb,Sr)Al3(PO4)(SO4)(OH)6 | [18] | |||||||
Tsumebite | Pb2Cu(PO4,SO4)(OH) | [19] | |||||||
Delvauxite | CaFe43+(PO4,SO4)2(OH)8·4–6H2O | [20] | |||||||
Rossiantonite | Al3(PO4)(SO4)2(OH)2(H2O)10·4H2O | triclinic | P1 | a = 10.3410, b = 10.9600, c = 11.1446, α = 86.985, β = 65.727, γ = 75.064°, Z = 2 | 1110.5 | [21] | |||
Schlossmacherite | (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6 | [22] | |||||||
Arthurite | Cu(Fe3+)2(AsO4,PO4,SO4)2(O,OH)2·4(H2O) | [23] | |||||||
cobaltarthurite | [23] | ||||||||
Phosphoinnelite | Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3 | triclinic | P1? | a = 5.38, b = 7.10, c = 14.76; α = 99.00°, β = 94.94°, γ = 90.14° Z = 1 | 555 | 3.82 | biaxial (+), α = 1.730, β = 1.745, and γ = 1.764, 2V 90° | [24] | |
Francolite | (Ca, Mg, Sr, Na)10(PO4, SO4, CO3)6F2–3 | [25] | |||||||
Al4(UO2)2(PO4)4(SO4)(OH)2 · 18H2O | [26] | ||||||||
Al4(UO2)2(PO4)4(SO4)(OH)2 · 20H2O | [26] | ||||||||
Coconinoite | Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O | monoclinic | C2/c | a =12.45, b = 12.96, c = 17.22, β = 105.7° | [26] | ||||
xiangjiangite | Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 22H2O | tetragonal | a = 7.17 Å, b = 7.17 Å, c = 22.22 Å Z=1 | 1,142 | Biaxial (-) nα = 1.558 nβ = 1.576 nγ = 1.593 2V: 87° | [27] |
chem | mw | crystal system | space group | unit cell Å | volume | density | comment | references |
---|---|---|---|---|---|---|---|---|
[H4N+]2·HSO4−·H2PO4− | [28][29] | |||||||
NH4(HSO4)0.45(H2PO4)0.55 | orthorhombic | [30] | ||||||
18-crown[6]·[NH4][H2PO4]0.5[HSO4]0.5·H2O | orthrhombic | F2dd | a=8.710 b= 28.868 c=31.206 Z=16 | 7846 | 1.346 | dehydrate at 70° | [31] | |
[(C2H5)4N+]2·HSO4−·H2PO4− | Monoclinic | C2/c | a = 28.0787 b = 11.8671 c = 14.1533 β = 100.739° Z=8 | 4633.46 | 1.303 | colourless; decompose at 353K | [32] | |
(NH2CH2COOH)3(H2SO4)0.7(H3PO4)0.3 | monoclinic | called TGSP; colourless; ferroelectric, curie point 51 °C; pyroelectric | ||||||
Na(HSO4)(H3PO4) | monoclinic | P 21 | a = 5.449, b = 6.832, c = 8.718, β = 95.88°, Z = 2 | 322.8 | [33] | |||
K2(HSO4)(H2PO4) | monoclinic | P 21/c | a = 11.150, b = 7.371, c = 9.436, β = 92.29°, Z = 4 | 774.9 | [33] | |||
K4(HSO4)3(H2PO4) | triclinic | P 1 | a = 7.217, b = 7.521, c = 7.574, α = 71.52°, β = 88.28°, γ = 86.20°, Z = 1 | 389.1 | [33] | |||
K4(PO2F2)2(S2O7) | 534.46 | monoclinic | C2/c | a = 13.00, b = 7.543, c = 19.01, β = 130.07°, Z = 4 | 1426.5 | 2.489 | colourless; pyrosulfate + difluorophosphate | [34] |
K3[O3SOPO2OSO3] | [35] | |||||||
H1−xTi2(PO4)3−x(SO4)x (x=0.5–1) | [36] | |||||||
Na2MgTi(SO4)(PO4)2 | trigonal | R3c | a=8.4796 c=21.8091 Z=6 | 1358.1 | 2.818 | [37] | ||
K2MgTi(SO4)(PO4)2 | cubic | P213 | a=9.8743 Z=4 | 962.84 | 2.872 | [37] | ||
Ca10-xNax(PO4)6-x(SO4)xF2 | monoclinic | [38] | ||||||
NaFe2(PO4)(SO4)2 | hexagonal | R3c | a=8.4243 c=21.973 | [39] | ||||
NaFe1.4V0.6(PO4)(SO4)2 | [40] | |||||||
[Ni(C14H10N4)3]4(PO4)2(SO4) (C14H10N4=2,2'-bi-1H-benzimidazole) | 3331.96 | cubic | I43d | a = 24.964 Z=4 | 15558 | 1.423 | green | [41] |
Rb2(HSO4)(H2PO4) | monoclinic | P21/n | a=7.448, b=7.552, c=7.632, β=100.47°, Z=2 | 422.1 | [42][43] | |||
Rb2(HSO4)(H2PO4) | monoclinic | P21/c | a=11.555, b=7.536, c=9.593, β=91.56, Z=4 | 853.0 | at 160K | [43] | ||
Rb4(HSO4)3(H2PO4) | orthorhombic | P21212 | a=7.612, b=14.795, c=7.446, Z=2 | 838.6 | [42][43] | |||
18-crown[6]·Rb[H2PO4]0.5[HSO4]0.5·3H2O | monoclinic | C2/c | a=19.802 b=8.447 c=25.777 β=101.00° Z=8 | 4232 | 1.572 | dehydrate at 70° | [31] | |
Rb2MgTi(SO4)(PO4)2 | [37] | |||||||
Sr4(PO4)2SO4 | [44] | |||||||
NaZrMg(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrCo(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrNi(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrCu(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrZn(PO4)(SO4)2 | hexagonal | R3c | [45] | |||||
NaZrAl(PO4)2(SO4) | hexagonal | R3c | [45] | |||||
NaZrFe(PO4)2(SO4) | hexagonal | R3c | [45] | |||||
H3OSb2(SO4)2(PO4) | triclinic | P1 | a=5.134 b=7.908 c=12.855, α=81.401° β=87.253° γ=86.49° | [46] | ||||
KSb2(SO4)2(PO4) | triclinic | P1 | a=5.1453 =7.9149 c=12.6146, α=82.054° β=87.715° γ=86.655° | [46] | ||||
RbSb2(SO4)2(PO4) | triclinic | P1 | a=5.1531 b=7.957 c=12.845, α=81.801° β=87.676° γ=86.703° | [46] | ||||
Cs2(HSO4)(H2PO4) | cubic | ao=4.926 | >105 °C but can be supercooled | [47] | ||||
Cs2(HSO4)(H2PO4) | monoclinic | P21/n | a = 7.856 b = 7.732 c = 7.827, β= 99.92° Z=2 | 468.3 | 3.261 | can substitute 2.3% ammonium; proton conductivity at 110 °C is 3×10−3 Ω−1cm−1 | [48][49] | |
Cs3(HSO4)2(H2PO4) | monoclinic | C2/c | a=19.824 b=7.859 c=19.047 β=100.20° Z=4 | 1387.2 | 3.302 | stable against water solution 298-313K; phase transition at 411K | [50] | |
Cs4(HSO4)3(H2PO4) | monoclinic | C2/c | a=19.945 b=7.8565 c=8.9949 β=100.119° Z=3 | 1387.5 | 3.301 | colourless | [51][52] | |
Cs5(HSO4)2(H2PO4)3 | cubic | I43d | a=14.5668 | over 381K goes to tetragonal a=4.965 c=5.016 | [53] | |||
Cs6H(HSO4)3(H2PO4)4 | cubic | I43d | a=14.4758 | 3033.38 | 3.236 | colourless | [54] | |
Cs5(HSO4)3(H2PO4)2 | monoclinic | C2/c | a=34.07 Å,b=7.661,c=9.158,β=90.44° | 2390 | 3.198 | [55] | ||
18-crown[6]·Cs[H2PO4]0.5[HSO4]0.5·3H2O | monoclinic | C2/c | a=19.840 b=8.460 c=26.19 β=101.14 Z=8 | 4313 | 1.689 | dehydrate at 70° | [31] | |
CsNH4(HSO4)(H2PO4) | [56] | |||||||
Cs3NH4(HSO4)3(H2PO4) | [56] | |||||||
Cs2MgTi(SO4)(PO4)2 | [37] | |||||||
Ba4(PO4)2SO4 | [44] | |||||||
NaBa6Zr(PO4)5SO4 | cubic | I43d | a = 10.5449 Z=4 | 1172.54 | eulytite mineral structure | [44] | ||
Ba2Sr2(PO4)2SO4 | [44] | |||||||
Ba3Sr(PO4)2SO4 | [44] | |||||||
Ce2O(HPO4)2(SO4). 4H2O | CeIV | [57] | ||||||
Ce2O(HPO4)2.4(SO4)0.6. 2H2O | CeIII | [58] | ||||||
[enH2]0.5[CeIII(PO4)(HSO4)(OH2)] | monoclinic | P21/a | a=12.999 b=7.150 c=9.212 β=95.33 | cream colour | [59] | |||
KSr2Eu(PO4)2SO4 | [44] | |||||||
RbSr2Eu(PO4)2SO4 | [44] | |||||||
CsSr2Eu(PO4)2SO4 | [44] | |||||||
[enH2]0.5[Ho(HPO4)(SO4)(H2O)] | monoclinic | P21/a | a = 12.938 b = 6.834 c = 9.100 β = 88.12° | [60] | ||||
Pb2Mg2(PO4)2SO4 | [44] | |||||||
MgPb3(PO4)2(SO4) | cubic | I43d | a = 10.299 Z=4 | 1092.4 | 5.67 | [61] | ||
CaPb3(PO4)2(SO4) | cubic | I43d | a = 10.296 Z=4 | 1091.5 | 5.77 | [61] | ||
MnPb3(PO4)2(SO4) | cubic | I43d | a = 10.258 Z=4 | 1079.4 | 5.92 | [61] | ||
CoPb3(PO4)2(SO4) | cubic | I43d | a = 10.356 Z=4 | 1110.6 | 5.78 | [61] | ||
NiPb3(PO4)2(SO4) | cubic | I43d | a = 10.434 Z=4 | 1135.9 | 5.65 | [61] | ||
CuPb3(PO4)2(SO4) | cubic | I43d | a = 10.422 Z=4 | 1132.0 | 5.70 | [61] | ||
ZnPb3(PO4)2(SO4) | cubic | I43d | a = 10.449 Z=4 | 1140.8 | 5.67 | [61] | ||
CdPb3(PO4)2(SO4) | cubic | I43d | a = 10.315 Z=4 | 1097.5 | 6.17 | [61] | ||
SrPb3(PO4)2(SO4) | cubic | I43d | a = 10.369 Z=4 | 1114.8 | 5.93 | [61] | ||
Th2(PO4)2SO4·2 H2O | decompose 450 °C | [62] |
A catenated sulfophosphate has the sulfur and phosphorus joined by an oxygen atom. In biochemistry, metabolism of sulfate may use such a group, for example with adenosine-5'-phosphosulfate.[63]
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