Isopentane
Chemical compound From Wikipedia, the free encyclopedia
Chemical compound From Wikipedia, the free encyclopedia
Isopentane, also called methylbutane or 2-methylbutane, is a branched-chain saturated hydrocarbon (an alkane) with five carbon atoms, with formula C
5H
12 or CH(CH
3)
2(C
2H
5).
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Names | |
---|---|
Preferred IUPAC name
2-Methylbutane[1] | |
Other names
Isopentane | |
Identifiers | |
3D model (JSmol) |
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1730723 | |
ChEBI | |
ChemSpider | |
ECHA InfoCard | 100.001.039 |
EC Number |
|
49318 | |
MeSH | isopentane |
PubChem CID |
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RTECS number |
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UNII | |
UN number | 1265 |
CompTox Dashboard (EPA) |
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Properties | |
C5H12 | |
Molar mass | 72.151 g·mol−1 |
Appearance | Colorless liquid |
Odor | Gasoline-like |
Density | 616 mg mL−1[2] |
Melting point | −161 to −159 °C; −258 to −254 °F; 112 to 114 K |
Boiling point | 27.8 to 28.2 °C; 81.9 to 82.7 °F; 300.9 to 301.3 K |
Vapor pressure | 76.992 kPa (at 20 °C) |
Henry's law constant (kH) |
7.2 nmol Pa−1 kg−1 |
UV-vis (λmax) | 192 nm |
Refractive index (nD) |
1.354 |
Viscosity | 0.214 cP (at 20 °C) |
Thermochemistry | |
Heat capacity (C) |
164.85 J K−1 mol−1 |
Std molar entropy (S⦵298) |
260.41 J K−1 mol−1 |
Std enthalpy of formation (ΔfH⦵298) |
−179.1–−177.3 kJ mol−1 |
Std enthalpy of combustion (ΔcH⦵298) |
~ 3.3 MJ mol−1, 19,664 Btu/lb |
Hazards | |
GHS labelling: | |
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Danger | |
H224, H301, H302, H305, H336, H411 | |
P210, P261, P273, P301+P310, P331 | |
NFPA 704 (fire diamond) | |
Flash point | −51 °C (−60 °F; 222 K) |
420 °C (788 °F; 693 K) | |
Explosive limits | 1.4–8.3% |
Related compounds | |
Related alkanes |
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Related compounds |
2-Ethyl-1-butanol |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Isopentane is a volatile and flammable liquid. It is one of three structural isomers with the molecular formula C5H12, the others being pentane (n-pentane) and neopentane (2,2-dimethylpropane).
Isopentane is commonly used in conjunction with liquid nitrogen to achieve a liquid bath temperature of −160 °C. Natural gas typically contains 1% or less isopentane,[3] but it is a significant component of natural gasoline.[4]
The traditional name isopentane was still retained in the 1993 IUPAC recommendations,[5][6] but is no longer recommended according to the 2013 recommendations.[1] The preferred IUPAC name is the systematic name 2-methylbutane. An isopentyl group is a subset of the generic pentyl group. It has the chemical structure -CH3CH2CH(CH3)2.
Isopentane is used in a closed loop in geothermal power production to drive turbines.[7]
Isopentane is used, in conjunction with dry ice or liquid nitrogen, to freeze tissues for cryosectioning in histology. [8]
Isopentane is a major component (sometimes 30% or more) of natural gasoline, an analog of common petroleum-derived gasoline that is condensed from natural gas.[4] It has a substantially higher octane rating (RON 93.7) than n-pentane (61.7), and therefore there is interest in conversion from the latter.[9]
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