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Alfonso's mother was María de las Mercedes, Princess of Asturias, but she died in childbirth in 1904. Alfonso XIII, King of Spain was unmarried at the time so as the Princess of the Asturias's eldest son, the young infante became heir-presumptive to the Spanish crown, though, unlike his mother, he never held the title of Prince of Asturias.[1] He was heir-presumptive until the birth of his cousin, Alfonso in 1907, to Alfonso XIII and Queen Victoria Eugenie.
Rodrigo Moreno y Borbón-Dos Sicilias (born 1 February 1962),[4] married to Casilda Guerrero-Burgos y Fernández de Córdoba, 21st Duchess of Cardona (born 1982).
Alicia Moreno y Borbón-Dos Sicilias (born 6 June 1964),[5] married to José Luis Hernández Eraso (born 1949),[6][7] with two children:
Cristina de Borbón-Dos Sicilias y Orleáns (born 16 March 1966),[21] married to Pedro López-Quesada y Fernández-Urrutia (born 26 July 1963),[22] with two children
María Paloma de Borbón-Dos Sicilias y Orleáns (born 5 April 1967),[23] married to Archduke Simeon of Austria (born 26 June 1959),[24] with five children
Isabel de Morales y Borbón-Dos Sicilias (born 10 April 1966),[40] married to Joaquín Galán y Otamendi,[41] with two children:
Carlota Galán y Borbón-Dos-Sicilias (born March 1998)[42]
Inés Galán y Borbón-Dos-Sicilias (born 3 January 2000)[43]
Eugenia de Morales y Borbón-Dos Sicilias (born 14 December 1967),[44] married to Iñigo Valdenebro y García de Polavieja,[45] with three children
Sonia de Morales y Borbón-Dos Sicilias (9 December 1969 – 26 July 2022),[46] married to Alejandro García-Atance y Leurquin (born 1974),[47] with two children
Manuel de Morales y Borbón-Dos Sicilias (born 16 December 1971),[48] married to Emma Ruiz de Azcárate y García de Lomas,[49] with two children
Mencía de Morales y Borbón-Dos Sicilias (born 25 November 1975)[50]
Por Real Decreto del 17 de octubre de 1904, gozó de todos los honores que le correspondían como heredero de la Corona, pero nunca ostentó el título de Príncipe de Asturias