Flory–Stockmayer theory
Theory of gel formation / From Wikipedia, the free encyclopedia
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Flory–Stockmayer theory is a theory governing the cross-linking and gelation of step-growth polymers.[1] The Flory–Stockmayer theory represents an advancement from the Carothers equation, allowing for the identification of the gel point for polymer synthesis not at stoichiometric balance.[1] The theory was initially conceptualized by Paul Flory in 1941[1] and then was further developed by Walter Stockmayer in 1944 to include cross-linking with an arbitrary initial size distribution.[2] The Flory–Stockmayer theory was the first theory investigating percolation processes.[3] Flory–Stockmayer theory is a special case of random graph theory of gelation.[4]