Dobson unit

The Dobson unit (DU) is a unit of measurement of the amount of a trace gas in a vertical column through the Earth's atmosphere. It originated by, and continues to be primarily used in respect to, the study of atmospheric ozone, whose total column amount, usually termed "total ozone", and sometimes "column abundance", is dominated by the high concentrations of ozone in the stratospheric ozone layer.

The Dobson unit is defined as the thickness (in units of 10 μm) of that layer of pure gas which would be formed by the total column amount at standard conditions for temperature and pressure (STP).^[1][2] This is sometimes referred to as a 'milli-atmo-centimeter'. A typical column amount of 300 DU of atmospheric ozone therefore would form a 3 mm layer of pure gas at the surface of the Earth if its temperature and pressure conformed to STP.

The Dobson unit is named after Gordon Dobson, a researcher at the University of Oxford who in the 1920s built the first instrument to measure total ozone from the ground, making use of a double prism monochromator to measure the differential absorption of different bands of solar ultraviolet radiation by the ozone layer. This instrument, called the Dobson ozone spectrophotometer, has formed the backbone of the global network for monitoring atmospheric ozone^[3] and was the source of the discovery in 1984 of the Antarctic ozone hole.^[4]

Ozone

NASA uses a baseline value of 220 DU for ozone. This was chosen as the starting point for observations of the Antarctic ozone hole, since values of less than 220 Dobson units were not found before 1979. Also, from direct measurements over Antarctica, a column ozone level of less than 220 Dobson units is a result of the ozone loss from chlorine and bromine compounds.^[5]

Sulfur dioxide

In addition, Dobson units are often used to describe total column densities of sulfur dioxide, which occurs in the atmosphere in small amounts due to the combustion of fossil fuels, from biological processes releasing dimethyl sulfide, or by natural combustion such as forest fires. Large amounts of sulfur dioxide may be released into the atmosphere as well by volcanic eruptions. The Dobson unit is used to describe total column amounts of sulfur dioxide because it appeared in the early days of ozone remote sensing on ultraviolet satellite instruments (such as TOMS).

Derivation

The Dobson unit arises from the ideal gas law

${\displaystyle PV=nRT,}$

where P and V are pressure and volume respectively, and n, R and T are the number of moles of gas, the gas constant (8.314 J/(mol·K)), and T is temperature in kelvins (K).

The number density of air is the number of molecules or atoms per unit volume:

${\displaystyle n_{\text{air}}={\frac {A_{av}n}{V}},}$

and when plugged into the real gas law, the number density of air is found by using pressure, temperature and the real gas constant:

${\displaystyle n_{\text{air}}={\frac {A_{av}P}{RT}}.}$

The number density (molecules/volume) of air at standard temperature and pressure (T = 273 K and P = 101325 Pa) is, by using this equation,

${\displaystyle n_{\text{air}}={\frac {A_{av}P}{RT}}={\frac {(6.02\times 10^{23}\,{\frac {\text{molecules}}{\text{mol}}})\cdot (101325~{\text{Pa}})}{8.314{\frac {\text{J}}{\text{mol K}}}\cdot 273~{\text{K}}}}.}$

With some unit conversions of joules to pascal cubic meters, the equation for molecules/volume is

${\displaystyle {\frac {(6.02\times 10^{23}~{\frac {\text{molecules}}{\text{mol}}})\cdot (101325~{\text{Pa}})}{8.314~{\frac {{\text{Pa}}\,{\text{m}}^{3}}{\text{mol K}}}\cdot 273~{\text{K}}}}=2.69\times 10^{25}~{\text{molecules}}\cdot {\text{m}}^{-3}.}$

A Dobson unit is the total amount of a trace gas per unit area. In atmospheric sciences, this is referred to as a column density. How, though, are units of molecules per cubic meter, a volume, to be converted to molecules per square centimeter, an area? This must be done by integration. To get the column density, integrate the total column over a height. Per the definition of Dobson units, 1 DU = 0.01 mm of trace gas when compressed down to sea level at standard temperature and pressure. So integrating the number density of air from 0 to 0.01 mm, it becomes equal to 1 DU:

${\displaystyle \int _{0~{\text{mm}}}^{0.01~{\text{mm}}}(2.69\times 10^{25}~{\text{molecules}}\cdot {\text{m}}^{-3})\,\mathrm {d} x=2.69\times 10^{25}~{\text{molecules}}\cdot {\text{m}}^{-3}\cdot 0.01~{\text{mm}}-2.69\times 10^{25}~{\text{molecules}}\cdot {\text{m}}^{-3}\cdot 0~{\text{mm}}}$

${\displaystyle {}=2.69\times 10^{25}~{\text{molecules}}\cdot {\text{m}}^{-3}\cdot 10^{-5}~{\text{m}}=2.69\times 10^{20}~{\text{molecules}}\cdot {\text{m}}^{-2}.}$

Thus the value of 1 DU is 2.69×10²⁰ molecules per meter squared.

References

1. "Ozone Hole Watch: Facts About Dobson Units".
2. IUPAC, Compendium of Chemical Terminology, 2nd ed. (the "Gold Book") (1997). Online corrected version: (2006–) "Dobson unit in atmospheric chemistry". doi:10.1351/goldbook.D01827
3. Staehelin, Johannes (2008). "Global atmospheric ozone monitoring". WMO Bulletin. 57 (1). Archived from the original on December 18, 2023.
4. Farman, J. C.; Gardiner, B. G.; Shankin, J. D. (1985). "Large losses of total ozone in Antarctica reveal seasonal ClO_x/NO_x interaction". Nature. 315 (16 May 1985): 207–210. Bibcode:1985Natur.315..207F. doi:10.1038/315207a0.
5. "Ozone Hole Watch". NASA. Retrieved 2007-10-21.