Metallophilic interaction
Non-covalent attraction between heavy metal atoms / From Wikipedia, the free encyclopedia
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In chemistry, a metallophilic interaction is defined as a type of non-covalent attraction between heavy metal atoms. The atoms are often within Van der Waals distance of each other and are about as strong as hydrogen bonds.[1] The effect can be intramolecular or intermolecular. Intermolecular metallophilic interactions can lead to formation of supramolecular assemblies whose properties vary with the choice of element and oxidation states of the metal atoms and the attachment of various ligands to them.[2]
The nature of such interactions remains the subject of vigorous debate with recent studies emphasizing that the metallophilic interaction is repulsive due to strong metal-metal Pauli exclusion principle repulsion.[3]