八氟萘是一种有机化合物,为萘的氢原子全部被氟取代的化合物,化学式为C10F8。它是单斜晶系的晶体,空间群P21/c。[3]它可由八氯萘和氟化钾在环丁砜中于235 °C反应制得。[4]全氟十氢萘在催化剂和氯化汞的存在下可以被镁或铝还原为八氟萘。[5]在氯化铵的存在下,它可以被锌粉在氨水中还原为1,2,4,5,6,8-六氟萘。[6]
Robbins, Andrew J.; Ng, William T. K.; Jochym, Dominik; Keal, Thomas W.; Clark, Stewart J.; Tozer, David J.; Hodgkinson, Paul. Combining insights from solid-state NMR and first principles calculation: applications to the 19F NMR of octafluoronaphthalene. Physical Chemistry Chemical Physics. 2007, 9 (19): 2389. ISSN 1463-9076. doi:10.1039/b701291h.
Yakobson, G. G.; Shteingarts, V. D.; Vorozhtsov, N. N., Jr. Synthesis of octafluoronaphthalene and decafluorodiphenyl. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1964. 8: 1551. ISSN: 0002-3353.
Bagryanskaya, Irina Yu.; Gatilov, Yuri V.; Lork, Enno; Mews, Rüdiger; Shakirov, Makhmut M.; Watson, Paul G.; Zibarev, Andrey V. Molecular complexes of octafluoronaphthalene with acyclic and heterocyclic sulfur–nitrogen compounds. Journal of Fluorine Chemistry. 2002, 116 (2): 149–156. ISSN 0022-1139. doi:10.1016/S0022-1139(02)00127-6.
Fuller, G. 1165. Preparation of polyfluoroaromatic compounds by the reaction of perhalogeno-aromatic compounds with potassium fluoride in sulpholan. Journal of the Chemical Society (Resumed). 1965: 6264. ISSN 0368-1769. doi:10.1039/jr9650006264.