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2-氰基-7-氮杂螺[3.5]壬烷-7-甲酸叔丁酯
化合物 / 維基百科,自由的 encyclopedia
2-氰基-7-氮杂螺[3.5]壬烷-7-甲酸叔丁酯是一种有机化合物,化学式为C14H22N2O2。它可由2-碘-7-氮杂螺[3.5]壬烷-7-甲酸叔丁酯和三甲基氰硅烷在碘化亚铜催化下、六氟磷酸二苯基碘、碳酸钾存在下于光照下反应制得;[2]或由7-叔丁氧羰基-7-氮杂螺[3.5]壬烷-2-酮和对甲苯磺酰甲基异腈在叔丁醇钠存在下反应得到。[1]
参考文献
- Chemical and Pharmaceutical Bulletin. 2004. 52 (6). doi:10.1248/cpb.52.675.
- The Merger of Aryl Radical-Mediated Halogen-Atom Transfer (XAT) and Copper Catalysis for the Modular Cross-Coupling-Type Functionalization of Alkyl Iodides. ACS Catal. 2023, 13, 7, 4985–4991. doi:10.1021/acscatal.3c00571.