铪酸锶是一种无机化合物,化学式为SrHfO3,存在无水物和二水合物。[4]
铪酸锶可以HfO(NO3)2·2H2O和SrCO3为原料制备。先将硝酸盐溶于水,按化学计量比加入SrCO3,在水中,HfO(NO3)2发生水解:
- HfO(NO3)2 + 2 H2O → Hf(OH)4 + 2 HNO3
水解产生的HNO3作用于SrCO3:
- 2 HNO3 + SrCO3 → Sr(NO3)2 + H2O + CO2↑
最后,将溶液蒸干,在高温下,Hf(OH)4分解为HfO2,Sr(NO3)2先分解为Sr(NO2)2,然后进一步分解为SrO,高于700℃时,两者反应,得到产物SrHfO3:[5]
- SrO + HfO2 → SrHfO3
铪酸锶也可以通过在电化学电池中的阳极转换反应制备,所用电压高达210V,电极温度控制在300 K。铪箔未沉积的部分需要用1:1的硝酸和氢氟酸清洗。[6]铪酸锶的薄膜还可以通过Hf对SrO2靶的气相沉积来制备。[7]在Si(100)底物上的等离子气相沉积也能够制得产物,反应中用(MeCp)2Hf(OMe)将会提高生长速率。[8]
铪酸锶参杂某些金属(如铈),可以得到闪烁陶瓷粉体材料。[9]
Feteira, Antonio; Sinclair, Derek C.; Rajab, Khalid Z.; Lanagan, Michael T. Crystal Structure and Microwave Dielectric Properties of Alkaline-Earth Hafnates, AHfO3 (A=Ba, Sr, Ca). Journal of the American Ceramic Society. 2008, 91 (3): 893 – 901. doi:10.1111/j.1551-2916.2007.02134.x.
Yamanaka, Shinsuke; Maekawa, Takuji; Muta, Hiroaki; Matsuda, Tetsushi; Kobayashi, Shin-ichi; Kurosaki, Ken. Thermal and mechanical properties of SrHfO3. Journal of alloys and compounds. 2004, 381 (1): 295–300.
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K. Black, M. Werner, R. Rowlands–Jones, et al. SrHfO3 Films Grown on Si(100) by Plasma-Assisted Atomic Layer Deposition. Chem. Mater., 2011. 23(10): 2518-2520
刘亚慧, 柏朝晖. 碱土铪酸盐闪烁陶瓷粉体的制备与表征. 化学工程与装备, 2009(10):33-35
- Red'ko, V.P.; Shevchenko, A.V.; Lopato, L.M. Polimorfizm gafnata i tsirkoniya strontsiya [Polymorphism of strontium hafnate and zirconate]. Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, 1988. 24(12): 2027-2030
- Ma, W., Li, P., Dong, H. et al. Y2O3 and Yb2O3 Co-doped Strontium Hafnate as a New Thermal Barrier Coating Material (页面存档备份,存于互联网档案馆). J Therm Spray Tech (2014) 23: 154. doi:10.1007/s11666-013-0006-9