苊蒽
化合物 / 維基百科,自由的 encyclopedia
苊蒽[3](英語:aceanthrylene)是一種稠環有機化合物,化學式為C16H10。它可以蒽和草醯氯為原料,經多步反應製得。[2]它可以被肼還原為1,2-二氫苊蒽(維基數據所列:Q27155948);[2]或被鈉在液氨中還原為2,6-二氫苊蒽。[4][5]它可以和羰基鐵[6]或羰基釕[4]形成配合物。
參考文獻
- Sangaiah, R.; Gold, A. (1985). A synthesis of aceanthrylene. Organic Preparations and Procedures International, 17 (1), 53–56. doi:10.1080/00304948509355469
- B. F. Plummer, Z. Y. Al-Saigh, and M. Arfan. Synthesis of aceanthrylene. J. Org. Chem. 1984, 49, 11, 2069–2071. doi:10.1021/jo00185a065.
- 中國化學會有機化合物命名審定委員會. 有機化合物命名原則 2017. 科學出版社. pp 70. ISBN 978-7-03-055295-2
- Hideo Nagashima, Akihiro Suzuki, Mitsuharu Nobata, and Kenji Itoh. Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbonyl Cluster as a Template to Control the Hydrogenation Site: First Successful Isolation of 4,5-Dihydroacenaphthylene and 4,5-Dihydroaceanthrylene. J. Am. Chem. Soc. 1996, 118, 3, 687–688. doi:10.1021/ja953742e.
- Rabideau, Peter W. (2004). The Birch Reduction of Aromatic Compounds. Organic Reactions, 2004. doi:10.1002/0471264180.or042.01
- Shota Niibayashi, Kouki Matsubara, Masa-aki Haga, and Hideo Nagashima. Thermally Reversible Photochemical Haptotropic Rearrangement of Diiron Carbonyl Complexes Bearing a Bridging Acenaphthylene or Aceanthrylene Ligand. Organometallics 2004, 23, 4, 635–646. doi:10.1021/om034117i.
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