环己烷甲酸甲酯

环己烷甲酸甲酯是一种有机化合物，化学式为C₈H₁₄O₂。它可由环己烷甲酸和甲醇在硫酸存在下回流反应制得。^[2]

环己烷甲酸甲酯
识别
CAS号	4630-82-4  Y
SMILES	O=C(OC)C1CCCCC1
性质
化学式	C8H14O2
摩尔质量	142.2 g·mol−1
外观	液体
沸点	180 °C[1]
相关物质
相关化学品	3,4-环氧环己烷甲酸甲酯
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

反应

环己烷甲酸甲酯可以被红铝还原为环己烷甲醛（维基数据所列：Q72459569）。^[3]

它和正辛醇在三氟甲磺酸五氟苯铵催化下于甲苯中反应，可以得到环己烷甲酸辛酯。^[4]

参考文献

1. Kirillov, N.F., Nikiforova, E.A., Vasyanin, A.N. et al. Synthesis of 16-aryl-15-oxadispiro[5.1.5.3]hexadecane-7,14-diones by reformatsky reaction. Russ J Org Chem 51, 513–517 (2015). doi:10.1134/S1070428015040089
2. José Maurício dos Santos Filho, Marcos Venícius Batista de Souza Castro. Synthesis, structural characterization, and antimicrobial activity of novel ferrocene-N-acyl hydrazones designed by means of molecular simplification strategy Celebrating the 100th anniversary of the birth of Professor Paulo Freire. Journal of Organometallic Chemistry. 2022. 979. 122488. doi:10.1016/j.jorganchem.2022.122488
3. Malek, Jaroslav. Reductions by metal alkoxyaluminum hydrides. Part II. Carboxylic acids and derivatives, nitrogen compounds, and sulfur compounds. Organic Reactions, 2004. 36. doi:10.1002/0471264180.or036.03.
4. Funatomi, Takashi; Wakasugi, Kazunori; Misaki, Tomonori; Tanabe, Yoo. Pentafluorophenylammonium triflate (PFPAT): An efficient, practical, and cost-effective catalyst for esterification, thioesterification, transesterification, and macrolactone formation. Green Chemistry, 2006. 8 (12). 1022-1027. doi:10.1039/b609181b.