叠氮化铵是叠氮酸的铵盐,化学式为NH4N3。与其他无机叠氮化合物类似,这种无色晶体具有爆炸性,尽管敏感度很低。NH4N3有生理活性:少量吸入会导致头痛和心悸。它最早由西奥多·库尔提乌斯(Theodor Curtius)在1890年于其他叠氮化物一起制得。
结构
叠氮化铵是离子化合物,几乎不溶于苯,它的含氮量高达93%。
参考资料
- Yakovleva, G. S.; Kurbangalina, R. Kh.; Stesik, L. N. Detonation properties of ammonium azide. Combustion Explosion and Shock Waves. 1977, 13: 405. doi:10.1007/BF00740326.
- Salim de Amorim, Helio; do Amaral, M. R.; Pattison P.; Ludka I. P.; Mendes, J. C. Ammonium azide: A Commented Example of an Ab Initio Structure (Re-)Determination From X-Ray Diffraction (PDF). Revista de la Sociedad Quimica de México. 2002, 45 (4): 313–319 [2020-11-07]. (原始内容存档 (PDF)于2012-04-06).
- Curtius, Th. Ueber Stickstoffwasserstoffsäure (Azoimid) N3H. Berichte der deutschen chemischen Gesellschaft. 1890, 23: 3023. doi:10.1002/cber.189002302232.
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