沃尔夫重排反应(Wolff重排反应),即:α-重氮酮在光、[1]热[2]或过渡金属催化剂(如氧化银)作用下,放出氮气生成卡宾中间体,然后发生1,2-重排反应生成烯酮。[3][4][5]该反应由陆德维希·沃尔夫在1912年发现。[6]
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