化學中,八面體形分子構型指的是一個分子中,中心原子上連有六個基團或配體而形成八面體的分子構型。理想的正八面體形分子屬於Oh點群,例如六氟化硫SF6、六羰基鉬Mo(CO)6等。使用「八面體」時比較隨意,一般不考慮配體本身的形狀,如[Co(NH3)6]3+在考慮N-H鍵時並不屬於八面體,但仍稱其為八面體型分子。[1]
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