沃爾夫重排反應（Wolff重排反應），即：α-重氮酮在光、[1]熱[2]或過渡金屬催化劑（如氧化銀）作用下，放出氮氣生成卡賓中間體，然後發生1,2-重排反應生成烯酮。[3][4][5]該反應由陸德維希·沃爾夫在1912年發現。[6]
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