穆員（?—?），字與直，唐朝懷州河內（今河南省沁陽市）人，穆寧的第三子。
穆員工文辭，尚節義。韋夏卿與穆員、齊映、穆員之兄穆贊相友善。杜亞為東都留守，闢為穆員從事、檢校員外郎。東都留守杜亞懷疑東都留守將令狐運搶劫轉運絲絹，令判官穆員及從事張弘靖一起審理此事。穆員與張弘靖都認為令狐運職在牙門，必不為盜。杜亞不聽，將穆員、張弘靖趕出幕府。穆員官至侍御史，早卒，有文集十卷。穆員兄弟被人用「珍味」比喻：穆贊俗而有格，為酪；穆質美而多入，為酥；穆員為醍醐；穆賞為乳腐。
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