George Green, An Essay on the Application of Mathematical Analysis to the Theories of Electricity and Magnetism (Nottingham, England: T. Wheelhouse, 1828). Green did not actually derive the form of "Green's theorem" which appears in this article; rather, he derived a form of the "divergence theorem", which appears on pages 10-12 (頁面存檔備份,存於網際網路檔案館) of his Essay.
In 1846, the form of "Green's theorem" which appears in this article was first published, without proof, in an article by Augustin Cauchy: A. Cauchy (1846) "Sur les intégrales qui s'étendent à tous les points d'une courbe fermée" (On integrals that extend over all of the points of a closed curve), Comptes rendus, 23: 251-255. (The equation appears at the bottom of page 254, where (S) denotes the line integral of a function k along the curve s that encloses the area S.)
A proof of the theorem was finally provided in 1851 by Bernhard Riemann in his inaugural dissertation: Bernhard Riemann (1851) Grundlagen für eine allgemeine Theorie der Functionen einer veränderlichen complexen Grösse (頁面存檔備份,存於網際網路檔案館) (Basis for a general theory of functions of a variable complex quantity), (Göttingen, (Germany): Adalbert Rente, 1867); see pages 8 - 9.