六氟合铜(IV)酸铯是一种红色晶体,化学式为Cs
2
CuF
6
,其中铜的氧化态是很罕见的+4。它可以由CsCuCl
3
氟化铯气在高压下反应制备。[2]

Quick Facts 六氟合铜(IV)酸铯, 识别 ...
六氟合铜(IV)酸铯
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CAS号 43070-30-0  checkY
SMILES
 
  • [Cs+].[Cs+].F[Cu-2](F)(F)(F)(F)F
性质
化学式 Cs2CuF6
摩尔质量 443.35 g·mol−1
外观 红橙色固体[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。
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扩展阅读

  • Harnischmacher, Werner; Hoppe, Rudolf. Vierwertiges Kupfer: Cs2[CuF6]. Angewandte Chemie. 1973, 85 (13): 590. doi:10.1002/ange.19730851312.
  • Müller, Bernd G. Fluoride mit Kupfer, Silber, Gold und Palladium. Angewandte Chemie. 1987, 99 (11): 1120. doi:10.1002/ange.19870991105.
  • Popova, T. V.; Aksenova, N. V. Complexes of Copper in Unstable Oxidation States. Russian Journal of Coordination Chemistry. 2003, 29 (11): 743. doi:10.1023/B:RUCO.0000003432.39025.cc.
  • Grannec, J. Some physical properties of d-transition metal fluorides in unusual oxidation states. Journal of Fluorine Chemistry. 1984, 25: 83. doi:10.1016/S0022-1139(00)81198-7.

参考资料

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