1,2,4-三硝基苯是一种有机化合物,化学式为C6H3N3O6,它是三硝基苯的同分异构体之一。它可由2,4-二硝基氟苯和亚硝酸钠在18-冠-6的存在下反应得到。[2]它在甲醇中于60 °C可以被含氢氧化钠的硼氢化钠还原,生成1,3-二硝基苯、1,4-二硝基苯和2,4-二硝基苯酚,占比分别为35%、24%、22%。[3]
参考文献
Borsche, W. β-Nitroarylhydroxylamines. I. β-2,4- and β-2,6-dinitrophenylhydroxylamine. Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen, 1923. 56B: 1494-1501. ISSN 0365-9488. CODEN BDCBAD.
Badea, Florin; Stoica, Alice; Ionita, Petre; Caproiu, Miron T.; Constantinescu, Titus. Nitration of some di- and trinitrohalobenzenes with solid sodium nitrite in the presence of 18-crown-6. Revue Roumaine de Chimie, 2000. 44 (4): 351-356. ISSN 0035-3930. CODEN RRCHAX.
Dale J, Vikersveen L. The reaction of nitrobenzenes with sodium borohydride; a novel reductive coupling to diphenylamine derivatives. Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry, 1988, 42(6): 354-361.
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