铬酸镍

铬酸镍
	IUPAC名; 铬酸镍(II)
英文名	Nickel chromate
识别
CAS号	14721-18-7
PubChem	61767
ChemSpider	55656
SMILES	[O-][Cr](=O)(=O)[O-].[Ni+2];
InChI	1S/Cr.Ni.4O/q;+2;;;2*-1;
InChIKey	QGAXAFUJMMYEPE-UHFFFAOYSA-N
EINECS	238-766-5
性质
化学式	NiCrO4
摩尔质量	174.71 g/mol g·mol⁻¹
外观	暗红褐色粉末
溶解性（水）	难溶
溶解性	可溶于盐酸
危险性
	GHS危险性符号;
GHS提示词	危险
H-术语	H272, H334, H317, H350, H372, H410
P-术语	P221, P273, P201, P308+P313
闪点	不可燃
相关物质
其他阴离子	钼酸镍; 钨酸镍
其他阳离子	铬酸钾; 铬酸钴
相关化学品	亚铬酸镍
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

铬酸镍是一种无机化合物，化学式为NiCrO₄，是可溶于酸的红褐色固体，对热稳定。该化合物可能会引起肿瘤或基因突变，对野生动物尤为突出。^[3]

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铬酸镍可由三氧化二铬和氧化镍的混合物在700 °C至800°C于1000个氧压下灼烧得到，若在535°C和7.3巴的氧气中反应，则需要数天。^[4]如果压力太低但温度高于660°C，则会产生镍铬尖晶石NiCr₂O₄（亚铬酸镍）。^[4]

Karin Brandt也通过水热反应制备了铬酸镍。^[5]^[6]用CrO2−
4沉淀Ni²⁺，可以得到棕色的水合物。^[7]

性质

铬酸镍的结构和钒酸铬（CrVO₄）相同，它属正交晶系，晶胞参数为a=5.482 Å，b=8.237 Å，c=6.147 Å。^[6]^[8]

铬酸镍在低氧压下于600°C分解：^[4]

4 NiCrO₄ → 2 NiCr₂O₄ + 2 NiO + 3 O₂↑

参考文献

[1]
Perry, Dale L. Handbook of Inorganic Compounds, Second Edition. CRC Press. : 290 [2017-08-19]. ISBN 9781439814628. （原始内容存档于2017-12-24）（英语）.
[2]
铬酸镍(II)水合物化学品安全技术说明书. ThermoFisher Scientific. [2017-08-19]
[3]
Eisler, R. (1998). Nickel Hazards to Fish, Wildlife, and Invertebrates: a Synoptic Review. Laurel: U.S. Geological Survey
[4]
Muller, Olaf; Roy, Rustum; White, William B. Phase Equilibria in the Systems NiO-Cr2,O3,-O2, MgO-Cr2O3-O2, and CdO-Cr2,O3,-O2, at High Oxygen Pressures. Journal of the American Ceramic Society. December 1968, 51 (12): 693–699. doi:10.1111/j.1151-2916.1968.tb15930.x.
[5]
Brandt, Karin. X-Ray Analysis of CrVO4 and isomorphous compounds. Arkiv for Kemi, Mineralogi och Geologi. 1943, 17A (6): 1–13. (not consulted)
[6]
Muller, Olaf; White, William B.; Roy, Rustum. X-ray diffraction study of the chromates of nickel, magnesium and cadmium. Zeitschrift für Kristallographie. September 1969, 130 (1-6): 112–120. doi:10.1524/zkri.1969.130.1-6.112.
[7]
Bronowska, W; Staszak, Z; Daszkiewicz, M; Cieślak-Golonka, M; Wojciechowska, A. Systematic investigation of the [Ni2+–phen–CrO42−] system; dichromate species isolated from alkaline solutions. Polyhedron. May 2002, 21 (9-10): 997–1003. doi:10.1016/S0277-5387(02)00912-9.
[8]
Baran, E. J. Materials belonging to the CrVO4 structure type: preparation, crystal chemistry and physicochemical properties. Journal of Materials Science. May 1998, 33 (10): 2479–2497. doi:10.1023/A:1004380530309.

[1] [1]
Perry, Dale L. Handbook of Inorganic Compounds, Second Edition. CRC Press. : 290 [2017-08-19]. ISBN 9781439814628. （原始内容存档于2017-12-24）（英语）.

[tf-2] [2]
铬酸镍(II)水合物化学品安全技术说明书. ThermoFisher Scientific. [2017-08-19]

[3] [3]
Eisler, R. (1998). Nickel Hazards to Fish, Wildlife, and Invertebrates: a Synoptic Review. Laurel: U.S. Geological Survey

[mull68-4] [4]
Muller, Olaf; Roy, Rustum; White, William B. Phase Equilibria in the Systems NiO-Cr2,O3,-O2, MgO-Cr2O3-O2, and CdO-Cr2,O3,-O2, at High Oxygen Pressures. Journal of the American Ceramic Society. December 1968, 51 (12): 693–699. doi:10.1111/j.1151-2916.1968.tb15930.x.

[5] [5]
Brandt, Karin. X-Ray Analysis of CrVO4 and isomorphous compounds. Arkiv for Kemi, Mineralogi och Geologi. 1943, 17A (6): 1–13. (not consulted)

[mull69-6] [6]
Muller, Olaf; White, William B.; Roy, Rustum. X-ray diffraction study of the chromates of nickel, magnesium and cadmium. Zeitschrift für Kristallographie. September 1969, 130 (1-6): 112–120. doi:10.1524/zkri.1969.130.1-6.112.

[bron-7] [7]
Bronowska, W; Staszak, Z; Daszkiewicz, M; Cieślak-Golonka, M; Wojciechowska, A. Systematic investigation of the [Ni2+–phen–CrO42−] system; dichromate species isolated from alkaline solutions. Polyhedron. May 2002, 21 (9-10): 997–1003. doi:10.1016/S0277-5387(02)00912-9.

[8] [8]
Baran, E. J. Materials belonging to the CrVO4 structure type: preparation, crystal chemistry and physicochemical properties. Journal of Materials Science. May 1998, 33 (10): 2479–2497. doi:10.1023/A:1004380530309.

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制备

性质

相关化合物

参考文献

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铬酸镍