硒氰酸盐

硒氰酸盐
识别
CAS号	5749-48-4
PubChem	76961
SMILES	[Se-]C#N;
性质
化学式	SeCN−
摩尔质量	104.98 g·mol⁻¹
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

硒氰酸盐是一类含有硒氰酸根离子（SeCN⁻）的盐类，常见的有硒氰酸钾、硒氰酸钠等。其酸HNCSe只存在于溶液中。^[1]

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性质

硒氰酸盐在盐酸中不稳定，放出氰化氢并析出红硒：

SeCN⁻ + H⁺ → HCN + Se

硒氰酸根离子可以多聚，形成含有诸如(SeCN)₃^-、(NCSe)₂I^-的化合物。

硒氰酸的Cd²⁺、Hg²⁺、Pb²⁺、Ag⁺盐都是难溶于水的固体。硒氰酸铵不稳定，肼盐则存在着如下平衡：N₂H₅NCSe ↔ H₂N⁻CSe⁻NH⁻NH₂。Fe²⁺盐的制备，无论是固体还是溶液，都未曾得到过^[2]，而铁单质亦可使SeCN⁻分解，产生CN⁻并析出Se^[3]，尽管如此，其配合物是已知的。^[4]

硒氰酸根和其它卤素或拟卤素的活性比较如下（越在左侧越容易被氧化）：^[1]

SeCN⁻ > I⁻ > SCN⁻ > CN⁻ > Br⁻ > N₃^- > Cl⁻ > OCN⁻ > CNO⁻ > F⁻

参考文献

[1]
Golub, A M; Skopenko, Viktor V. METAL SELENOCYANATES AND THEIR PROPERTIES. Russian Chemical Reviews (IOP Publishing). 1965-12-31, 34 (12): 901–908. ISSN 0036-021X. doi:10.1070/rc1965v034n12abeh001573.
[2]
Crookes, William Von. Ueber die Selencyanide. Annalen der Chemie und Pharmacie. 1851, 78 (2): 177–187. ISSN 0075-4617. doi:10.1002/jlac.18510780207.
[3]
Xiaoguang Meng, Sunbaek Bang, George P Korfiatis. Removal of selenocyanate from water using elemental iron. Water Research, 2002. 30(15): 3867–3873
[4]
Christopher J. Adams, et al. Iron(II) thio- and selenocyanate coordination networks containing 3,3'-bipyridine. Cryst Eng Comm, 2011, 13, 4909

参见

[Golub-1] [1]
Golub, A M; Skopenko, Viktor V. METAL SELENOCYANATES AND THEIR PROPERTIES. Russian Chemical Reviews (IOP Publishing). 1965-12-31, 34 (12): 901–908. ISSN 0036-021X. doi:10.1070/rc1965v034n12abeh001573.

[2] [2]
Crookes, William Von. Ueber die Selencyanide. Annalen der Chemie und Pharmacie. 1851, 78 (2): 177–187. ISSN 0075-4617. doi:10.1002/jlac.18510780207.

[3] [3]
Xiaoguang Meng, Sunbaek Bang, George P Korfiatis. Removal of selenocyanate from water using elemental iron. Water Research, 2002. 30(15): 3867–3873

[4] [4]
Christopher J. Adams, et al. Iron(II) thio- and selenocyanate coordination networks containing 3,3'-bipyridine. Cryst Eng Comm, 2011, 13, 4909

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