α,α,α-三硝基甲苯

α,α,α-三硝基甲苯是一种有机化合物，化学式为C₇H₅N₃O₆，是三硝基甲苯的同分异构体之一。它可由α,α-二硝基苄基钾和四氧化二氮在三氯甲烷中反应得到。^[2]它可以用于制备α-C-硝基腙。^[3]

α,α,α-三硝基甲苯
英文名	(Trinitromethyl)benzene α,α,α-Trinitrotoluene
别名	(三硝基甲基)苯
识别
CAS号	67483-29-8  Y
SMILES	c1ccccc1C([N+](=O)[O-])([N+](=O)[O-])[N+](=O)[O-]
性质
化学式	C7H5N3O6
摩尔质量	227.13 g·mol−1
熔点	4.5 °C（277.6 K）[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

参考文献

1. Titov, A. I.; Smirnov, V. V. Effect of complex formation, ionization, and isomerization of organic compounds on their chemical activity in nitration. Synthesis of phenyltrinitromethane and its properties. Doklady Akademii Nauk SSSR, 1952. 83. 243-246. ISSN: 0002-3264.
2. Makhova, N. N.; Ovchinnikov, I. V.; Dubonos, V. G.; Strelenko, Yu. A.; Khmel?nitski, L. I. New methods for preparation of nitrile oxides and the corresponding disubstituted furoxans by reaction of N₂O₄ with salts of substituted dinitromethanes. Izvestiya Akademii Nauk, Seriya Khimicheskaya, 1993. 1: 147-151.
3. Shvarts, I. Sh.; Krayushkin, M. M.; Sevost'yanova, V. V.; Yarovenko, V. N. Synthesis and properties of α-C-nitrohydrazones. 2. Reaction of hydrazines with trinitromethyl components（俄文）. Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya. 1979. 5. 1069-1073.