2-甲基十一烷

2-甲基十一烷是一种烷烃，化学式为C₁₂H₂₆。它可由壬基溴化锌（维基数据所列：Q82286492）和2-溴丙烷在双(1,5-环辛二烯)镍和双取代𫫇唑基吡啶的催化下反应制得；^[2]1-(5-羟甲基-2-呋喃基)-5-甲基-1-己烯-3-酮在钯和三氟甲磺酸铕催化下氢化，也能得到2-甲基十一烷。^[3]它存在于番石榴、沉香等植物的叶中。^[4][5]

2-甲基十一烷
英文名	2-Methylundecane.png
识别
CAS号	7045-71-8  Y
SMILES	CCCCCCCCCC(C)C
性质
化学式	C12H26
摩尔质量	170.33 g·mol−1
沸点	208.9 °C[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

参考文献

1. Mukwembi, S., Nyabadza, F. A new model for predicting boiling points of alkanes. Sci Rep 11, 24261 (2021). doi:10.1038/s41598-021-03541-z.
2. Paul A. Wender, Thomas E. Smith, Hung A. Duong, Janis Louie, Eric A. Standley, Sarah Z. Tasker. Bis(1,5-cyclooctadiene)nickel(0). Encyclopedia of Reagents for Organic Synthesis, 2015. doi:10.1002/047084289X.rb118.pub3.
3. Juha Keskiväli , Pauli Wrigstedt , Kalle Lagerblom , Timo Repo. One-step Pd/C and Eu(OTf)3 catalyzed hydrodeoxygenation of branched C11 and C12 biomass-based furans to the corresponding alkanes. Applied Catalysis A: General, 2017. 534. doi:10.1016/j.apcata.2017.01.017.
4. Shaza H. Aly; et al. Chemical Constituents, Antioxidant, and Enzyme Inhibitory Activities Supported by In-Silico Study of n-Hexane Extract and Essential Oil of Guava Leaves. Molecules 2022, 27(24), 8979. doi:10.3390/molecules27248979.
5. Ridwanti Batubara; et al. Rasayan J. Chem., 14(2), 751-759 (2021). doi:10.31788/ RJC.2021.1426021.

延伸阅读

• Yury V. Kissin (1990). Relative reactivities of alkanes in catalytic cracking reactions. Journal of Catalysis, 126(2), 600–609. doi:10.1016/0021-9517(90)90023-d
• Yury V. Kissin (1994). Degenerate Non-primary Products in Catalytic Cracking of Isoalkanes. Journal of Catalysis, 146(2), 358–369.doi:10.1006/jcat.1994.1074