球二孢菌素

球二孢菌素是一种有机化合物，化学式为C₇H₁₂O₃，它是一种由青霉菌产生的抗生素真菌毒素。^[2]它可由2-羟基-3-甲基-4-乙烯基四氢呋喃在氯化钯和乙酸铜的催化下被氧气氧化制得。^[3]

球二孢菌素
IUPAC名 1-(5-Hydroxy-4-methyloxolan-3-yl)ethanone
英文名	Botryodiplodin
识别
CAS号	1314905-22-0  Y 27098-03-9（3R,4S）  Y
PubChem	33701
ChemSpider	31076
SMILES	CC1C(COC1O)C(=O)C
ChEBI	168857
性质
化学式	C7H12O3
摩尔质量	144.17 g·mol−1
熔点	42 °C[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

参考文献

1. Sen Gupta, R.; Chandran, R. R.; Divekar, P. V. Botryodiplodin, a new antibiotic from Botryodiplodia theobromae. I. Production, isolation, and biological properties. Indian Journal of Experimental Biology, 1966. 4 (3): 152-153. ISSN 0019-5189.
2. Cabedo, N; López-Gresa, MP; Primo, J; Ciavatta, ML; González-Mas, MC. Isolation and structural elucidation of eight new related analogues of the mycotoxin (−)-botryodiplodin from Penicillium coalescens. Journal of Agricultural and Food Chemistry. 2007, 55 (17): 6977–83. PMID 17628075. doi:10.1021/jf071568v. hdl:10251/99756 .
3. Robert Nouguier, Stéphane Gastaldi, Didier Stien, Michèle Bertrand, Félix Villar, Olivier Andrey, Philippe Renaud. Synthesis of (±)- and (−)-botryodiplodin using stereoselective radical cyclizations of acyclic esters and acetals. Tetrahedron: Asymmetry. 2003-10, 14 (19): 3005–3018 [2021-09-11]. doi:10.1016/j.tetasy.2003.06.004 （英语）.