六氟合铜(IV)酸铯是一种红色晶体,化学式为Cs
2CuF
6,其中铜的氧化态是很罕见的+4。它可以由CsCuCl
3与氟化铯、氟气在高压下反应制备。[2]
六氟合铜(IV)酸铯 | |
---|---|
识别 | |
CAS号 | 43070-30-0 |
SMILES |
|
性质 | |
化学式 | Cs2CuF6 |
摩尔质量 | 443.35 g·mol−1 |
外观 | 红橙色固体[1] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
扩展阅读
- Harnischmacher, Werner; Hoppe, Rudolf. Vierwertiges Kupfer: Cs2[CuF6]. Angewandte Chemie. 1973, 85 (13): 590. doi:10.1002/ange.19730851312.
- Müller, Bernd G. Fluoride mit Kupfer, Silber, Gold und Palladium. Angewandte Chemie. 1987, 99 (11): 1120. doi:10.1002/ange.19870991105.
- Popova, T. V.; Aksenova, N. V. Complexes of Copper in Unstable Oxidation States. Russian Journal of Coordination Chemistry. 2003, 29 (11): 743. doi:10.1023/B:RUCO.0000003432.39025.cc.
- Grannec, J. Some physical properties of d-transition metal fluorides in unusual oxidation states. Journal of Fluorine Chemistry. 1984, 25: 83. doi:10.1016/S0022-1139(00)81198-7.
参考资料
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