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疊氮者,離子或官能團也。三氮成鏈,其間共以雙鍵或單鍵,為擬鹵素焉。疊氮化合物性不穩,多易爆而具毒性,故需慎處之。
夫非官疊氮化物者,乃疊氮酸及其衍生物也。裂解則可得其單質:
2AgN3→3N2↑+2Ag
亦有生其氮化物者:
3LiN3 → Li3N + 4N2↑
疊氮化鈉可施與安全氣囊,疊氮化鉛則可起爆也。
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