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Izraz kovalentna je v zvezi z vezavo prvič uporabljena leta 1919 od Irvinga Langmuirja v Journal of the American Chemical Society v članku z naslovom The Arrangement of Electrons in Atoms and Molekules. Langmuir je napisal, da bi vsi morali označiti z kovalentno vezjo število parov elektronov, kar si jih dam atom deli s sosedom.
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