Amülopektiin on hargneva ahelaga glükoosijääkidest koosnev homopolüsahhariid. Hargnemine toimub ~30 glükoosijäägi tagant α1→6 glükosiidsideme abil. Lineaarses ahelas on glükoosijäägid omavahel seotud α1→4 glükosiidsidemega.
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