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Carmine (/ˈkɑːrmən, ˈkɑːrmaɪn/) – also called cochineal (when it is extracted from the cochineal insect), cochineal extract, crimson lake, or carmine lake – is a pigment of a bright-red color obtained from the aluminium complex derived from carminic acid. Specific code names for the pigment include natural red 4, C.I. 75470, or E120. Carmine is also a general term for a particularly deep-red color.
The English word "carmine" is derived from the French word carmin (12th century), from Medieval Latin carminium, and from Persian قرمز qirmiz ("crimson"), which itself derives from Middle Persian carmir ("red, crimson"). The Persian term carmir is likely cognate with Sanskrit krimiga ("insect-produced"), from krmi ("worm, insect"). The Persian word for "worm, insect" is kirm, and in Iran (Persia) the red colorant carmine was extracted from the bodies of dead female insects such as Kermes vermilio and cochineal. The form of the term may also have been influenced in Latin by minium ("red lead, cinnabar"), said to be of Iberian origin.
The word "carmine" has been used as a color name as early as 1799. It is a popular food color, used in yogurt, candy, gelatin, meat, and beverages including fruit juices.
Female Dactylopius coccus aka Cochineal bugs were already used for their red coloring power as far back as in the 700 BC. South American civilizations crushed the bugs present on cacti to extract the carmine they contain. Carmine pigment was extensively used by the Aztec civilization to dye textiles. It was imported later to Europe during the 16th century.[1]
Red is a color often associated with power and social status. Through the centuries, red has been worn by tribal chiefs, kings and queens, and military officers.[2]: 166
In the 17th century, carmine dye made of cochineal and tin was used to color British military uniforms. This vibrant color was also present in aristocrats' closet.
The trade of cochineal was a major source of income for the Spanish Crown.
"In the 1610s, for instance, twenty-five pounds of cochineal cost sixty times more than an equivalent weight of sugar."[2]: 64
The Spanish Crown had a monopoly on the production of cochineal bugs until the 1820 when the French learned to cultivate them. Later, German and British scientists created a chemical red dye. The combination of these factors contributed to the end of the Spanish monopoly and considerably lowered the price of this red gold. As a consequence, carmine red became accessible to a wider audience.
In general, the history of the trade of cochineal remains linked to slavery and triangular trade.
The pigment is produced from carminic acid, which is extracted from some scale insects such as the cochineal scale (Prima), and certain Porphyrophora species (Armenian cochineal and Polish cochineal). Cochineal is now farmed.
Carmine is a colorant used in the manufacture of artificial flowers, paints, crimson ink, rouge, food coloring, cosmetics, and some medications.[citation needed]
Synthetic carminic acid is complex to produce. Therefore, natural cochineal carmine is predominant on the market. However, its instability makes its use difficult in dye and painting, but a still a great ingredient for cosmetics.[1]: 263
To prepare carmine, the powdered scale insect bodies are boiled in an ammonia or sodium carbonate solution. After separating the insoluble matter, the extract is treated with alum to precipitate the red solid. This precipitate is called "carmine lake" or "crimson lake". Purity of color is ensured by the absence of iron. Stannous chloride, citric acid, borax, or gelatin may be added to modify the precipitation. The traditional crimson color is affected not only by carminic acid but also by choice of its chelating metal salt ion. For shades of purple, lime is added to the alum.[citation needed]
To obtain 1 pound of red dye, one needs 70,000 cochineal bugs.[2]: 82
Thanks to liquid chromatography and a diode array detector combined with a mass spectrometer with a quadruple-time-of-flight analyzer (LC-DAD-QTOF), scientists can detect the presence of carminic acid. This further enables a better identification of works of art as it helps to determine the date and origin of the pigment.[2]: 102
Scientific methods now allow us to distinguish among the different species of cochineal used in artworks.
As confirmed by reflectance spectroscopy, carmine reflects mostly red light, i.e., wavelengths longer than about 603 nm. Its hue is comprised between 497 nm for a dark purplish red and 612 nm for a vibrant red.[1]: 264
The hue is the aspect of the color determined by wavelength. Carmine's hue is dependent on the metallic ions combined to cochineal while making the pigment. For instance, cochineal carmine and zinc or aluminum gives a crimson hue.[1]: 266
The translucence of carmine depends on its binding medium. Mixed with oil, carmine remains translucent and adequate for glazes. Combined with tempera or glue, carmine turns opaque.[1]: 264
The traditional hue's value is around 6.35, a yellowish hue 5.5, and a purplish hue 3.32.[1]: 264
According to Russells' classification,[3]: 144 carmine is the most unstable pigment. The hues of this red pigment, including "cochineal, carmine, and crimson lake" are very subject to fade into brownish tones.[3]: 141
Carmine is a fugitive color, whose fading is influenced by different factors such as light, humidity, or even the glass color of the frame.[3]
In painting, its durability also depends on the type of binding. For instance, pigments are more resistant if mixed with linseed oil rather than with gum-arabic.[4]: 1 Cochineal carmine is very sensitive to light in watercolor.[5] Carmine can be stabilized "thanks to precipitation of cochineal-based red lake with alum, and thanks to the inclusion of tin salt mordants."[6]: 698–9
Carmine's vibrant color is extensively used in Art and has been since its creation in Antiquity.
Carmine was used in dyeing textiles and in painting since antiquity. It is not very stable in oil paint, and its use ceased after new and better red pigments became available. Best examples of the use of carmine cochineal red are present among Inca remains such as textile artifacts. The Aztecs who occupied lands on the present Mexico also resorted to the female cocci's coloring power.
In Europe, the 16th century Italian painter Jacopo Tintoretto used carmine in several of his paintings. The most notable being Portrait of Vincenzo Morosini[7] (1575-80) and Christ Washing the Feet of the Disciples[8].(1575-80)
Madame de Pompadour by Francois Boucher, French painter of the eighteenth century, extensively relies on cochineal. This is reminded in the pinkish color of the ribbons, the cameo, the dress, and Madame de Pompadour's pink cheeks as she is doing her make-up with cochineal based cosmetics. In this particular painting, cochineal is synonymous with femininity and high society.
Carmine was also used by recent artists such as Vincent Van Gogh in Bedroom in Arles (1889). The once reddish floor of the bedroom is painted with carmine cochineal lake, geranium lake and indigo. Nowadays, the floor has lost its initial red color and is blueish because of the fugitive red pigments.[9]
Joseph Mallord William Turner, a 19th century English painter used cochineal carmine as the analysis of his palettes revealed.[10] The fading of this pigment affected his canvases changing his luminous reddish skies overtime as in The Fighting Temeraire (1839).[11]
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