In rough analogy, a POVM is to a PVM what a mixed state is to a pure state. Mixed states are needed to specify the state of a subsystem of a larger system (see purification of quantum state); analogously, POVMs are necessary to describe the effect on a subsystem of a projective measurement performed on a larger system.
POVMs are the most general kind of measurement in quantum mechanics, and can also be used in quantum field theory.[1] They are extensively used in the field of quantum information.
In quantum mechanics, the key property of a POVM is that it determines a probability measure on the outcome space, so that can be interpreted as the probability of the event when measuring a quantum state.
In the discrete case, the POVM element is associated with the measurement outcome , such that the probability of obtaining it when making a quantum measurement on the quantum state is given by
,
where is the trace operator. When the quantum state being measured is a pure state this formula reduces to
The probability formulas for a PVM are the same as for the POVM. An important difference is that the elements of a POVM are not necessarily orthogonal. As a consequence, the number of elements of the POVM can be larger than the dimension of the Hilbert space they act in. On the other hand, the number of elements of the PVM is at most the dimension of the Hilbert space.
Note: An alternate spelling of this is "Neumark's Theorem"
Naimark's dilation theorem[4] shows how POVMs can be obtained from PVMs acting on a larger space. This result is of critical importance in quantum mechanics, as it gives a way to physically realize POVM measurements.[5]:285
In the simplest case, of a POVM with a finite number of elements acting on a finite-dimensional Hilbert space, Naimark's theorem says that if is a POVM acting on a Hilbert space of dimension , then there exists a PVM acting on a Hilbert space of dimension and an isometry such that for all ,
For the particular case of a rank-1 POVM, i.e., when for some (unnormalized) vectors , this isometry can be constructed as[5]:285
and the PVM is given simply by . Note that here .
In the general case, the isometry and PVM can be constructed by defining[6][7], , and
Note that here , so this is a more wasteful construction.
In either case, the probability of obtaining outcome with this PVM, and the state suitably transformed by the isometry, is the same as the probability of obtaining it with the original POVM:
This construction can be turned into a recipe for a physical realisation of the POVM by extending the isometry into a unitary , that is, finding such that
for from 1 to . This can always be done.
The recipe for realizing the POVM described by on a quantum state is then to embed the quantum state in the Hilbert space , evolve it with the unitary , and make the projective measurement described by the PVM .
Post-measurement state
The post-measurement state is not determined by the POVM itself, but rather by the PVM that physically realizes it. Since there are infinitely many different PVMs that realize the same POVM, the operators alone do not determine what the post-measurement state will be. To see that, note that for any unitary the operators
will also have the property that , so that using the isometry
in the second construction above will also implement the same POVM. In the case where the state being measured is in a pure state , the resulting unitary takes it together with the ancilla to state
and the projective measurement on the ancilla will collapse to the state[3]:84
on obtaining result . When the state being measured is described by a density matrix , the corresponding post-measurement state is given by
.
We see therefore that the post-measurement state depends explicitly on the unitary . Note that while is always Hermitian, generally, does not have to be Hermitian.
Another difference from the projective measurements is that a POVM measurement is in general not repeatable. If on the first measurement result was obtained, the probability of obtaining a different result on a second measurement is
,
which can be nonzero if and are not orthogonal. In a projective measurement these operators are always orthogonal and therefore the measurement is always repeatable.
Suppose you have a quantum system with a 2-dimensional Hilbert space that you know is in either the state or the state , and you want to determine which one it is. If and are orthogonal, this task is easy: the set will form a PVM, and a projective measurement in this basis will determine the state with certainty. If, however, and are not orthogonal, this task is impossible, in the sense that there is no measurement, either PVM or POVM, that will distinguish them with certainty.[3]:87 The impossibility of perfectly discriminating between non-orthogonal states is the basis for quantum information protocols such as quantum cryptography, quantum coin flipping, and quantum money.
The task of unambiguous quantum state discrimination (UQSD) is the next best thing: to never make a mistake about whether the state is or , at the cost of sometimes having an inconclusive result. It is possible to do this with projective measurements.[8] For example, if you measure the PVM , where is the quantum state orthogonal to , and obtain result , then you know with certainty that the state was . If the result was , then it is inconclusive. The analogous reasoning holds for the PVM , where is the state orthogonal to .
This is unsatisfactory, though, as you can't detect both and with a single measurement, and the probability of getting a conclusive result is smaller than with POVMs. The POVM that gives the highest probability of a conclusive outcome in this task is given by [8][9]
where
Note that , so when outcome is obtained we are certain that the quantum state is , and when outcome is obtained we are certain that the quantum state is .
The probability of having a conclusive outcome is given by
when the quantum system is in state or with the same probability. This result is known as the Ivanović-Dieks-Peres limit, named after the authors who pioneered UQSD research.[10][11][12]
Since the POVMs are rank-1, we can use the simple case of the construction above to obtain a projective measurement that physically realises this POVM. Labelling the three possible states of the enlarged Hilbert space as , , and ?}}\rangle }
, we see that the resulting unitary takes the state to
?}}\rangle ,}
and similarly it takes the state to
?}}\rangle .}
A projective measurement then gives the desired results with the same probabilities as the POVM.
This POVM has been used to experimentally distinguish non-orthogonal polarisation states of a photon. The realisation of the POVM with a projective measurement was slightly different from the one described here.[13][14]
I. M. Gelfand and M. A. Neumark, On the embedding of normed rings into the ring of operators in Hilbert space, Rec. Math. [Mat. Sbornik] N.S. 12(54) (1943), 197–213.