Peroxynitric acid or peroxonitric acid is a chemical compound with the formula HNO
4
. It is an oxyacid of nitrogen, after peroxynitrous acid.

Quick Facts Names, Identifiers ...
Peroxynitric acid
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Names
Preferred IUPAC name
Hydroxy nitrate
Systematic IUPAC name
Hydroxy nitrate[1][2][3]
Identifiers
3D model (JSmol)
ChemSpider
  • Key: UUZZMWZGAZGXSF-UHFFFAOYSA-N checkY[Pubchem]
  • [N+](=O)([O-])OO
Properties
HNO4
Molar mass 79.01224 g/mol
Conjugate base Peroxynitrate
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Preparation

Peroxynitrate, the conjugate base of peroxynitric acid, is formed rapidly during decomposition of peroxynitrite in neutral conditions.[4]

Atmospheric chemistry

Peroxynitric acid is formed in the atmosphere, although it is unstable, it is important as a reservoir for NO2 through the reversible radical reaction:[5]

HO
2
NO
2
HO
2
+ NO
2

References

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