Fissile material

"Fissility" redirects here. For the topic in geology, see Fissility (geology).

In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy.^[1] A self-sustaining thermal chain reaction can only be achieved with fissile material. The predominant neutron energy in a system may be typified by either slow neutrons (i.e., a thermal system) or fast neutrons. Fissile material can be used to fuel thermal-neutron reactors, fast-neutron reactors and nuclear explosives.

Fissile vs fissionable

Region of relative stability: radium-226 to einsteinium-252

		88	89	90	91	92	93	94	95	96	97	98	99
154		Half-life Key   1   10  100    1k  10k 100k   1M  10M 100M   1G  10G (a)								250Cm		252Cf			154
153												251Cf	252Es		153
152										248Cm		250Cf			152
151										247Cm	248Bk	249Cf			151
150								244Pu		246Cm	247Bk				150
149										245Cm					149
148								242Pu	243Am	244Cm					148
147								241Pu	242m⁂	243Cm					147
146						238U		240Pu	241Am						146
145								239Pu							145
144						236U	237Np	238Pu							144
143						235U	236Np								143
142				232Th		234U	235Np	236Pu							142
141						233U									141
140		228Ra		230Th	231Pa	232U					Table Axes Neutrons (N) Protons (Z)				140
139				229Th											139
138		226Ra	227Ac	228Th											138
		88	89	90	91	92	93	94	95	96	97	98	99
Only nuclides with a half-life of at least one year are shown on this table.

The term fissile is distinct from fissionable. A nuclide that can undergo nuclear fission (even with a low probability) after capturing a neutron of high or low energy^[2] is referred to as fissionable. A fissionable nuclide that can undergo fission with a high probability after capturing a low-energy thermal neutron is referred to as fissile.^[3] Fissionable materials include those (such as uranium-238) for which fission can be induced only by high-energy neutrons. As a result, fissile materials (such as uranium-235) are a subset of fissionable materials.

Uranium-235 fissions with low-energy thermal neutrons because the binding energy resulting from the absorption of a neutron is greater than the critical energy required for fission; therefore uranium-235 is fissile. By contrast, the binding energy released by uranium-238 absorbing a thermal neutron is less than the critical energy, so the neutron must possess additional energy for fission to be possible. Consequently, uranium-238 is fissionable but not fissile.^[4][5]

An alternative definition defines fissile nuclides as those nuclides that can be made to undergo nuclear fission (i.e., are fissionable) and also produce neutrons from such fission that can sustain a nuclear chain reaction in the correct setting. Under this definition, the only nuclides that are fissionable but not fissile are those nuclides that can be made to undergo nuclear fission but produce insufficient neutrons, in either energy or number, to sustain a nuclear chain reaction. As such, while all fissile isotopes are fissionable, not all fissionable isotopes are fissile. In the arms control context, particularly in proposals for a Fissile Material Cutoff Treaty, the term fissile is often used to describe materials that can be used in the fission primary of a nuclear weapon.^[6] These are materials that sustain an explosive fast neutron nuclear fission chain reaction.

Under all definitions above, uranium-238 (²³⁸
U
) is fissionable, but not fissile. Neutrons produced by fission of ²³⁸
U
have lower energies than the original neutron (they behave as in an inelastic scattering), usually below 1 MeV (i.e., a speed of about 14,000 km/s), the fission threshold to cause subsequent fission of ²³⁸
U
, so fission of ²³⁸
U
does not sustain a nuclear chain reaction.

Fast fission of ²³⁸
U
in the secondary stage of a thermonuclear weapon, due to the production of high-energy neutrons from nuclear fusion, contributes greatly to the yield and to fallout of such weapons. Fast fission of ²³⁸
U
tampers has also been evident in pure fission weapons.^[7] The fast fission of ²³⁸
U
also makes a significant contribution to the power output of some fast-neutron reactors.

Fissile nuclides

Actinides and fission products by half-life v t e
Actinides[8] by decay chain				Half-life range (a)	Fission products of 235U by yield[9]
4n	4n + 1	4n + 2	4n + 3		4.5–7%	0.04–1.25%	<0.001%
228Ra№				4–6 a		155Euþ
248Bk[10]				> 9 a
244Cmƒ	241Puƒ	250Cf	227Ac№	10–29 a	90Sr	85Kr	113mCdþ
232Uƒ		238Puƒ	243Cmƒ	29–97 a	137Cs	151Smþ	121mSn
	249Cfƒ	242mAmƒ		141–351 a	No fission products have a half-life in the range of 100 a–210 ka ...
	241Amƒ		251Cfƒ[11]	430–900 a
		226Ra№	247Bk	1.3–1.6 ka
240Pu	229Th	246Cmƒ	243Amƒ	4.7–7.4 ka
	245Cmƒ	250Cm		8.3–8.5 ka
			239Puƒ	24.1 ka
		230Th№	231Pa№	32–76 ka
236Npƒ	233Uƒ	234U№		150–250 ka	99Tc₡	126Sn
248Cm		242Pu		327–375 ka		79Se₡
				1.33 Ma	135Cs₡
	237Npƒ			1.61–6.5 Ma	93Zr	107Pd
236U			247Cmƒ	15–24 Ma		129I₡
244Pu				80 Ma	... nor beyond 15.7 Ma[12]
232Th№		238U№	235Uƒ№	0.7–14.1 Ga
₡,  has thermal neutron capture cross section in the range of 8–50 barns ƒ,  fissile №,  primarily a naturally occurring radioactive material (NORM) þ,  neutron poison (thermal neutron capture cross section greater than 3k barns)

In general, most actinide isotopes with an odd neutron number are fissile. Most nuclear fuels have an odd atomic mass number (A = Z + N = the total number of nucleons), and an even atomic number Z. This implies an odd number of neutrons. Isotopes with an odd number of neutrons gain an extra 1 to 2 MeV of energy from absorbing an extra neutron, from the pairing effect which favors even numbers of both neutrons and protons. This energy is enough to supply the needed extra energy for fission by slower neutrons, which is important for making fissionable isotopes also fissile.

More generally, nuclides with an even number of protons and an even number of neutrons, and located near a well-known curve in nuclear physics of atomic number vs. atomic mass number are more stable than others; hence, they are less likely to undergo fission. They are more likely to "ignore" the neutron and let it go on its way, or else to absorb the neutron but without gaining enough energy from the process to deform the nucleus enough for it to fission. These "even-even" isotopes are also less likely to undergo spontaneous fission, and they also have relatively much longer partial half-lives for alpha or beta decay. Examples of these isotopes are uranium-238 and thorium-232. On the other hand, other than the lightest nuclides, nuclides with an odd number of protons and an odd number of neutrons (odd Z, odd N) are usually short-lived (a notable exception is neptunium-236 with a half-life of 154,000 years) because they readily decay by beta-particle emission to their isobars with an even number of protons and an even number of neutrons (even Z, even N) becoming much more stable. The physical basis for this phenomenon also comes from the pairing effect in nuclear binding energy, but this time from both proton–proton and neutron–neutron pairing. The relatively short half-life of such odd-odd heavy isotopes means that they are not available in quantity and are highly radioactive.

According to the fissility rule proposed by Yigal Ronen, for a heavy element with Z between 90 and 100, an isotope is fissile if and only if 2 × Z − N ∈ {41, 43, 45} (where N = number of neutrons and Z = number of protons), with a few exceptions.^[13][14] This rule holds for all but fourteen nuclides – seven that satisfy the criterion but are nonfissile, and seven that are fissile but do not satisfy the criterion.^{[note 1]}

Nuclear fuel

Main article: Nuclear fuel

To be a useful fuel for nuclear fission chain reactions, the material must:

• Be in the region of the binding energy curve where a fission chain reaction is possible (i.e., above radium)
• Have a high probability of fission on neutron capture
• Release more than one neutron on average per neutron capture. (Enough of them on each fission, to compensate for non-fissions and absorptions in non-fuel material)
• Have a reasonably long half-life
• Be available in suitable quantities.

Capture-fission ratios of fissile nuclides

Thermal neutrons[15]				Epithermal neutrons
σF (b)	σγ (b)	%		σF (b)	σγ (b)	%
531	46	8.0%	233U	760	140	16%
585	99	14.5%	235U	275	140	34%
750	271	26.5%	239Pu	300	200	40%
1010	361	26.3%	241Pu	570	160	22%

Fissile nuclides in nuclear fuels include:

• Uranium-233, bred from thorium-232 by neutron capture with intermediate decays steps omitted.
• Uranium-235, which occurs in natural uranium and enriched uranium
• Plutonium-239, bred from uranium-238 by neutron capture with intermediate decays steps omitted.
• Plutonium-241, bred from plutonium-240 directly by neutron capture.

Fissile nuclides do not have a 100% chance of undergoing fission on absorption of a neutron. The chance is dependent on the nuclide as well as neutron energy. For low and medium-energy neutrons, the neutron capture cross sections for fission (σ_F), the cross section for neutron capture with emission of a gamma ray (σ_γ), and the percentage of non-fissions are in the table at right.

Fertile nuclides in nuclear fuels include:

• Thorium-232, which breeds uranium-233 by neutron capture with intermediate decays steps omitted.
• Uranium-238, which breeds plutonium-239 by neutron capture with intermediate decays steps omitted.
• Plutonium-240, which breeds plutonium-241 directly by neutron capture.

See also

• Fertile material
• Fission product
• Special nuclear material

Notes

1. The fissile rule thus formulated indicates 33 isotopes as likely fissile: Th-225, 227, 229; Pa-228, 230, 232; U-231, 233, 235; Np-234, 236, 238; Pu-237, 239, 241; Am-240, 242, 244; Cm-243, 245, 247; Bk-246, 248, 250; Cf-249, 251, 253; Es-252, 254, 256; Fm-255, 257, 259. Only fourteen (including a long-lived metastable nuclear isomer) have half-lives of at least a year: Th-229, U-233, U-235, Np-236, Pu-239, Pu-241, Am-242m, Cm-243, Cm-245, Cm-247, Bk-248, Cf-249, Cf-251 and Es-252. Of these, only U-235 is naturally occurring. It is possible to breed U-233 and Pu-239 from more common naturally occurring isotopes (Th-232 and U-238 respectively) by single neutron capture. The others are typically produced in smaller quantities through further neutron absorption.

References

1. "NRC: Glossary -- Fissile material". www.nrc.gov.
2. "NRC: Glossary -- Fissionable material". www.nrc.gov.
3. "Slides-Part one: Kinetics". UNENE University Network of Excellence in Nuclear Engineering. Retrieved 3 January 2013.
4. James J. Duderstadt and Louis J. Hamilton (1976). Nuclear Reactor Analysis. John Wiley & Sons, Inc. ISBN 0-471-22363-8.
5. John R. Lamarsh and Anthony John Baratta (Third Edition) (2001). Introduction to Nuclear Engineering. Prentice Hall. ISBN 0-201-82498-1.
6. Fissile Materials and Nuclear Weapons Archived 2012-02-06 at the Wayback Machine, International Panel on Fissile Materials
7. Semkow, Thomas; Parekh, Pravin; Haines, Douglas (2006). "Modeling the Effects of the Trinity Test". Applied Modeling and Computations in Nuclear Science. ACS Symposium Series. Vol. ACS Symposium Series. pp. 142–159. doi:10.1021/bk-2007-0945.ch011. ISBN 9780841239821.
8. Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
9. Specifically from thermal neutron fission of uranium-235, e.g. in a typical nuclear reactor.
10. Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. Bibcode:1965NucPh..71..299M. doi:10.1016/0029-5582(65)90719-4.
    "The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk²⁴⁸ with a half-life greater than 9 [years]. No growth of Cf²⁴⁸ was detected, and a lower limit for the β⁻ half-life can be set at about 10⁴ [years]. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 [years]."
11. This is the heaviest nuclide with a half-life of at least four years before the "sea of instability".
12. Excluding those "classically stable" nuclides with half-lives significantly in excess of ²³²Th; e.g., while ^113mCd has a half-life of only fourteen years, that of ¹¹³Cd is eight quadrillion years.
13. Ronen Y., 2006. A rule for determining fissile isotopes. Nucl. Sci. Eng., 152:3, pages 334-335.
14. Ronen, Y. (2010). "Some remarks on the fissile isotopes". Annals of Nuclear Energy. 37 (12): 1783–1784. Bibcode:2010AnNuE..37.1783R. doi:10.1016/j.anucene.2010.07.006.
15. "Interactive Chart of Nuclides". Brookhaven National Laboratory. Archived from the original on 2017-01-24. Retrieved 2013-08-12.